Structure 1001236

1001235 << 1001236 >> 1001237
Original COD entry Download CIF Download DOT

Citation: Leclaire, A; Monier, J C; Raveau, B (1983). K~4~ Mo~8~ P~12~ O~52~, A Tunnel Structure Characterized by an Unusual Valence of Molybdenum. Journal of Solid State Chemistry, 48, pp. 147-153.

Formula: K4 Mo8 O52 P12

Chemical name: Tetrapotassium 52-oxo-octamolybdo(V)dodecaphosphate

Cell parameters:

  • a = 10.7433(16) Å
  • b = 14.0839(9) Å
  • c = 8.8519(7) Å
  • α = 90°
  • β = 126.42(1)°
  • γ = 90°

List type: noninterleaving

List: 3D

Combined 3D structure and graph

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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 1

Basis: (1;0;0 0;1;0 0;0;1)

Dimensionality: 3

Formula: Mo8 O52 P12 (Mo2 O13 P3)

Multiplicity: 1

Coordination sequences:

  • 1, 5, 5, 14, 10, 42, 25, 63, 34, 138
  • 2, 6, 4, 18, 11, 28, 18, 82, 50, 118
  • 2, 8, 6, 19, 13, 47, 30, 91, 50, 153
  • 2, 8, 6, 20, 14, 48, 29, 88, 49, 154
  • 2, 8, 7, 21, 12, 45, 30, 94, 50, 150
  • 2, 8, 7, 25, 16, 50, 29, 91, 46, 142
  • 2, 8, 7, 25, 17, 53, 28, 87, 46, 144
  • 4, 4, 16, 10, 28, 18, 77, 46, 114, 54
  • 4, 4, 20, 14, 35, 20, 80, 40, 96, 50
  • 6, 5, 14, 10, 42, 25, 63, 34, 138, 69
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