Structure 1001363

1001362 << 1001363 >> 1001364
Original COD entry Download CIF Download DOT

Citation: Leclaire, A; Lamire, M; Raveau, B (1988). Mo~4~ P~6~ Si~2~ O~25~, an Mo(^III^) phosphosilicate closely related to V~3~ P~5~ Si O~19~: oxygen non-stoichiometry in silicophosphates.. Acta Crystallographica C (39,1983-), 44, pp. 1181-1184.

Formula: Mo4 O25 P6 Si2

Chemical name: Tetramolybdenum(III) tecto-hexaphosphodisilicate

Cell parameters:

  • a = 14.705(4) Å
  • b = 14.705(4) Å
  • c = 7.3986(5) Å
  • α = 90°
  • β = 90°
  • γ = 120°

List type: noninterleaving

List: 3D

Combined 3D structure and graph

span 1 {1 1 1}
Ctrl-click to select multiple nodes

JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 1

Basis: (1;0;0 0;1;0 0;0;1)

Dimensionality: 3

Formula: Mo12 O75 P18 Si6 (Mo4 O25 P6 Si2)

Multiplicity: 1

Coordination sequences:

  • 2, 6, 6, 18, 18, 78, 60, 114, 116, 190
  • 2, 6, 6, 18, 18, 78, 60, 114, 116, 193
  • 2, 6, 7, 29, 29, 76, 71, 131, 129, 200
  • 2, 9, 12, 32, 35, 74, 73, 138, 131, 218
  • 2, 9, 12, 32, 35, 74, 73, 138, 132, 219
  • 2, 9, 12, 32, 35, 75, 72, 136, 131, 218
  • 2, 9, 12, 32, 36, 75, 73, 138, 132, 221
  • 2, 9, 12, 32, 36, 76, 72, 136, 131, 220
  • 2, 9, 12, 32, 36, 76, 72, 136, 132, 221
  • 3, 11, 11, 37, 32, 80, 71, 145, 125, 224
  • 4, 4, 12, 15, 63, 51, 102, 106, 171, 175
  • 4, 5, 23, 23, 51, 51, 117, 106, 166, 169
  • 7, 9, 21, 25, 60, 58, 102, 104, 197, 164
  • 7, 9, 21, 25, 61, 58, 102, 103, 195, 167
span 1 {1 1 1}