Structure 1001539

1001538 << 1001539 >> 1001540
Original COD entry Download CIF Download DOT

Citation: Benhamada, L; Grandin, A; Borel, M M; Leclaire, A; Raveau, B (1992). Na/2VP~2~O~8~: A Tetravalent Vanadium Diphosphate with a Layered Structure. Journal of Solid State Chemistry, 101, pp. 154-160.

Formula: Na2 O8 P2 V

Chemical name: Disodium phyllo-diphosphatovanadate(IV)

Cell parameters:

  • a = 7.7178(6) Å
  • b = 13.3233(8) Å
  • c = 6.287(3) Å
  • α = 90°
  • β = 99.49(1)°
  • γ = 90°

List type: interleaving

List: 2D

Combined 3D structure and graph

span 1 {1 1 1}
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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 2

Basis: (1;0;0 0;0;1)

Dimensionality: 2

Formula: O16 P4 V2 (O8 P2 V)

Multiplicity: 1

Coordination sequences:

  • 1, 3, 3, 12, 8, 25, 14, 42, 18, 50
  • 1, 5, 5, 14, 8, 28, 15, 42, 16, 48
  • 2, 6, 4, 19, 12, 29, 13, 45, 22, 57
  • 2, 8, 5, 15, 9, 30, 16, 45, 18, 53
  • 2, 8, 6, 17, 10, 36, 17, 44, 19, 58
  • 2, 8, 6, 20, 11, 32, 15, 45, 20, 56
  • 2, 8, 7, 21, 11, 34, 16, 46, 20, 57
  • 2, 8, 7, 22, 11, 33, 16, 46, 20, 58
  • 4, 3, 12, 8, 25, 14, 42, 18, 50, 22
  • 4, 4, 17, 10, 27, 12, 38, 20, 55, 20
  • 6, 5, 14, 8, 28, 15, 42, 16, 48, 25
span 1 {1 1 1}

CIF datablock 1, entity 2 of 2

Basis: (1;0;0 0;0;1)

Dimensionality: 2

Formula: O16 P4 V2 (O8 P2 V)

Multiplicity: 1

Coordination sequences:

  • 1, 3, 3, 12, 8, 25, 14, 42, 18, 50
  • 1, 5, 5, 14, 8, 28, 15, 42, 16, 48
  • 2, 6, 4, 19, 12, 29, 13, 45, 22, 57
  • 2, 8, 5, 15, 9, 30, 16, 45, 18, 53
  • 2, 8, 6, 17, 10, 36, 17, 44, 19, 58
  • 2, 8, 6, 20, 11, 32, 15, 45, 20, 56
  • 2, 8, 7, 21, 11, 34, 16, 46, 20, 57
  • 2, 8, 7, 22, 11, 33, 16, 46, 20, 58
  • 4, 3, 12, 8, 25, 14, 42, 18, 50, 22
  • 4, 4, 17, 10, 27, 12, 38, 20, 55, 20
  • 6, 5, 14, 8, 28, 15, 42, 16, 48, 25
span 1 {1 1 1}