Structure 1001568

1001567 << 1001568 >> 1001569
Original COD entry Download CIF Download DOT

Citation: Crespoa, P; Grandin, A; Borel, M M; Leclaire, A; Raveau, B (1993). A new mixed-valent vanadium phosphate with a tunnel structure Cd~5~V~3~P~6~O~25~. Journal of Solid State Chemistry, 105, pp. 307-312.

Formula: Cd5 O25 P6 V3

Chemical name: Pentacadmium tecto-divanado(III)vanado(IV)hexaphosphate

Cell parameters:

  • a = 16.861(1) Å
  • b = 4.710(1) Å
  • c = 24.160(2) Å
  • α = 90°
  • β = 103.07(1)°
  • γ = 90°

List type: noninterleaving

List: 3D

Combined 3D structure and graph

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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 1

Basis: (1;0;0 0;1;0 0;0;1)

Dimensionality: 3

Formula: Cd20 O100 P24 V12 (Cd5 O25 P6 V3)

Multiplicity: 1

Coordination sequences:

  • 1, 4, 8, 32, 38, 96, 120, 182, 226, 300
  • 2, 9, 16, 44, 58, 118, 136, 238, 263, 392
  • 3, 11, 16, 54, 60, 135, 138, 255, 294, 386
  • 3, 12, 17, 62, 66, 141, 177, 235, 304, 385
  • 3, 12, 18, 58, 60, 133, 150, 256, 307, 380
  • 3, 13, 16, 59, 60, 134, 163, 229, 299, 375
  • 3, 13, 18, 58, 65, 138, 159, 240, 305, 369
  • 3, 14, 21, 54, 59, 141, 141, 266, 279, 407
  • 3, 14, 21, 59, 77, 136, 177, 242, 322, 383
  • 3, 14, 21, 63, 76, 135, 177, 236, 339, 387
  • 3, 15, 21, 59, 77, 134, 184, 247, 336, 387
  • 3, 15, 22, 65, 76, 138, 186, 242, 317, 361
  • 3, 17, 23, 60, 90, 137, 177, 240, 341, 377
  • 5, 8, 32, 38, 96, 120, 182, 226, 300, 398
  • 5, 9, 28, 46, 84, 101, 196, 204, 347, 368
  • 5, 11, 34, 51, 96, 132, 192, 252, 330, 411
  • 5, 11, 36, 48, 96, 135, 186, 252, 317, 410
  • 6, 10, 31, 38, 101, 106, 196, 233, 322, 406
  • 6, 12, 38, 40, 96, 120, 206, 240, 326, 454
  • 7, 11, 35, 54, 105, 123, 196, 285, 311, 429
  • 8, 12, 41, 55, 101, 145, 194, 268, 308, 442
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