Structure 1001603

1001602 << 1001603 >> 1001604
Original COD entry Download CIF Download DOT

Citation: Guesdon, A; Borel, M M; Leclaire, A; Grandin, A; Raveau, B (1994). A mixed-valent molybdenum monophosphate with a "butterfly"-shaped tunnel structure Cs~6~Mo~7~O~9~(PO~4~)~7~ . H~2~O. Journal of Solid State Chemistry, 111, pp. 315-321.

Formula: Cs6 H2 Mo7 O38 P7

Chemical name: Hexacaesium tecto-pentamolybdo(V)dimolybdo(IV)heptaphosphate hydrate

Cell parameters:

  • a = 10.084(1) Å
  • b = 21.297(3) Å
  • c = 17.491(1) Å
  • α = 90°
  • β = 90°
  • γ = 90°

List type: noninterleaving

List: 3D

Combined 3D structure and graph

span 1 {1 1 1}
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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 1

Basis: (1;0;0 0;1;0 0;0;1)

Dimensionality: 3

Formula: Mo28 O148 P28 (Mo7 O37 P7)

Multiplicity: 1

Coordination sequences:

  • 1, 3, 3, 15, 15, 29, 19, 77, 66, 104
  • 1, 5, 6, 17, 10, 41, 35, 73, 54, 129
  • 1, 5, 6, 17, 10, 43, 36, 81, 42, 123
  • 1, 6, 8, 13, 12, 35, 47, 75, 58, 99
  • 2, 8, 6, 19, 14, 50, 38, 86, 62, 137
  • 2, 8, 6, 19, 14, 52, 38, 94, 50, 134
  • 2, 8, 6, 20, 16, 45, 37, 83, 77, 146
  • 2, 8, 7, 24, 16, 41, 39, 98, 72, 130
  • 2, 8, 7, 24, 18, 46, 36, 98, 78, 132
  • 2, 8, 7, 24, 18, 48, 35, 99, 63, 137
  • 2, 8, 8, 26, 12, 44, 44, 116, 58, 122
  • 2, 9, 6, 16, 12, 52, 42, 90, 40, 133
  • 2, 9, 7, 16, 16, 44, 49, 89, 67, 113
  • 2, 9, 9, 20, 20, 40, 46, 93, 83, 116
  • 2, 9, 9, 22, 17, 40, 48, 86, 98, 131
  • 2, 9, 9, 22, 17, 40, 48, 89, 94, 129
  • 2, 9, 10, 20, 15, 45, 49, 91, 83, 122
  • 2, 9, 10, 22, 16, 40, 50, 102, 83, 114
  • 2, 9, 11, 25, 17, 36, 50, 105, 92, 122
  • 3, 14, 6, 14, 14, 61, 44, 91, 40, 142
  • 3, 14, 8, 18, 11, 55, 52, 93, 63, 144
  • 4, 3, 15, 15, 29, 19, 77, 66, 104, 96
  • 4, 4, 17, 10, 27, 20, 87, 62, 113, 52
  • 4, 4, 18, 14, 27, 19, 72, 80, 119, 89
  • 4, 4, 20, 18, 25, 21, 79, 78, 117, 83
  • 6, 6, 17, 10, 41, 35, 73, 54, 129, 113
  • 6, 6, 17, 10, 43, 36, 81, 42, 123, 88
  • 7, 8, 13, 12, 35, 47, 75, 58, 99, 111
  • 7, 10, 18, 11, 36, 46, 77, 77, 113, 126
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