Structure 1001616

1001615 << 1001616 >> 1001617
Original COD entry Download CIF Download DOT

Citation: Leclaire, A; Chardon, J; Grandin, A; Borel, M M; Raveau, B (1994). The monophosphate Pb~2~V~2~VO(PO~4~)~4~: a tunnel structure with the mixed valence V(III)-V(IV). Journal of Solid State Chemistry, 108, pp. 291-298.

Formula: O17 P4 Pb2 V3

Chemical name: Dilead oxovanadium(IV) tecto-divanadato(III)tetraphosphate

Cell parameters:

  • a = 17.74699(200) Å
  • b = 18.05099(200) Å
  • c = 9.344(1) Å
  • α = 90°
  • β = 117.03(1)°
  • γ = 90°

List type: noninterleaving

List: 3D

Combined 3D structure and graph

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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 1

Basis: (1;0;0 0;1;0 0;0;1)

Dimensionality: 3

Formula: O136 P32 Pb16 V24 (O17 P4 Pb2 V3)

Multiplicity: 1

Coordination sequences:

  • 2, 8, 9, 29, 36, 70, 70, 140, 142, 237
  • 2, 8, 9, 29, 36, 71, 74, 130, 145, 231
  • 2, 8, 10, 28, 25, 69, 61, 140, 126, 220
  • 2, 8, 10, 29, 28, 76, 64, 158, 115, 253
  • 2, 8, 10, 29, 29, 80, 64, 138, 139, 229
  • 2, 8, 10, 30, 30, 76, 66, 141, 136, 227
  • 2, 8, 11, 29, 25, 71, 62, 144, 126, 222
  • 2, 8, 11, 31, 36, 80, 85, 145, 156, 235
  • 2, 8, 11, 33, 30, 80, 69, 154, 120, 242
  • 2, 8, 11, 34, 31, 77, 73, 147, 135, 232
  • 2, 9, 14, 33, 33, 85, 87, 154, 149, 244
  • 3, 5, 16, 17, 55, 53, 113, 105, 185, 199
  • 3, 7, 7, 28, 30, 80, 70, 140, 144, 228
  • 3, 8, 12, 38, 39, 90, 86, 156, 164, 252
  • 3, 10, 11, 35, 35, 87, 79, 160, 151, 245
  • 3, 11, 12, 33, 33, 93, 73, 166, 132, 260
  • 3, 11, 12, 33, 34, 88, 74, 163, 134, 265
  • 3, 11, 12, 36, 32, 78, 84, 152, 140, 237
  • 4, 5, 17, 19, 53, 43, 108, 98, 189, 193
  • 4, 5, 21, 22, 53, 48, 121, 106, 208, 171
  • 4, 5, 22, 22, 53, 51, 110, 109, 192, 190
  • 4, 6, 20, 21, 59, 59, 119, 124, 200, 203
  • 5, 8, 22, 26, 60, 67, 122, 125, 203, 212
  • 6, 7, 20, 29, 60, 66, 113, 128, 203, 212
  • 6, 8, 22, 18, 52, 50, 118, 110, 190, 170
  • 6, 8, 22, 20, 64, 58, 134, 98, 218, 178
  • 6, 8, 22, 22, 64, 60, 130, 119, 203, 198
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