Structure 1001858

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Original COD entry Download CIF Download DOT

Citation: Benmoussa, A; Borel, M M; Grandin, A; Leclaire, A; Raveau, B (1991). Structure of mixed-valent titanium silicophosphates, K Ti3 P6 Si2 O25 and Cs Ti3 P6 Si2 O25. Acta Crystallographica C (39,1983-), 47, pp. 936-938.

Formula: Cs O25 P6 Si2 Ti3

Chemical name: Caesium titanium disilicohexaphosphate (1/3/1)

Cell parameters:

  • a = 8.2145(6) Å
  • b = 8.2145(6) Å
  • c = 17.24899(100) Å
  • α = 90°
  • β = 90°
  • γ = 120°

List type: noninterleaving

List: 3D

Combined 3D structure and graph

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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 1

Basis: (1;0;0 0;1;0 0;0;1)

Dimensionality: 3

Formula: O50 P12 Si4 Ti6 (O25 P6 Si2 Ti3)

Multiplicity: 1

Coordination sequences:

  • 2, 6, 6, 18, 12, 54, 36, 90, 56, 188
  • 2, 6, 6, 24, 19, 57, 37, 107, 67, 184
  • 2, 8, 8, 25, 19, 57, 37, 115, 69, 192
  • 2, 8, 8, 26, 21, 66, 45, 119, 62, 168
  • 2, 8, 8, 27, 19, 54, 37, 112, 69, 196
  • 4, 4, 12, 12, 48, 30, 78, 49, 160, 98
  • 4, 4, 18, 15, 40, 26, 93, 59, 142, 76
  • 6, 6, 18, 13, 45, 30, 78, 47, 171, 105
  • 6, 6, 18, 14, 54, 42, 102, 48, 144, 84
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