Structure 1008525

1008524 << 1008525 >> 1008526
Original COD entry Download CIF Download DOT

Citation: Birdwishtell, T L T; Klein, C L; Jeffries, T; Stevens, E D; O'Connor, C J (1991). Synthesis and crystal structures of the layered I-III-V Zintl phases, K~4~In~4~X~6~, where X=As, Sb. Journal of Materials Chemistry, 1, pp. 555-558.

Formula: As6 In4 K4

Chemical name: Tetrapotassium phyllo-hexaarsenidotetraindate

Cell parameters:

  • a = 14.323(3) Å
  • b = 7.106(2) Å
  • c = 15.795(3) Å
  • α = 90°
  • β = 90.30(2)°
  • γ = 90°

List type: interleaving

List: 2D

Combined 3D structure and graph

span 1 {1 1 1}
Ctrl-click to select multiple nodes

JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 2

Basis: (1;0;0 0;1;0)

Dimensionality: 2

Formula: As12 In8 (As3 In2)

Multiplicity: 1

Coordination sequences:

  • 3, 7, 9, 21, 24, 25, 34, 36, 42, 48
  • 3, 7, 9, 21, 25, 23, 36, 35, 42, 48
  • 3, 9, 9, 23, 25, 25, 36, 36, 42, 50
  • 3, 9, 11, 21, 22, 29, 34, 38, 42, 50
  • 3, 12, 12, 19, 27, 26, 35, 41, 40, 52
  • 3, 12, 14, 17, 27, 26, 35, 40, 42, 50
  • 5, 8, 13, 22, 25, 26, 36, 38, 43, 52
  • 5, 8, 17, 18, 21, 34, 31, 38, 48, 44
span 1 {1 1 1}

CIF datablock 1, entity 2 of 2

Basis: (1;0;0 0;1;0)

Dimensionality: 2

Formula: As12 In8 (As3 In2)

Multiplicity: 1

Coordination sequences:

  • 3, 7, 9, 21, 24, 25, 34, 36, 42, 48
  • 3, 7, 9, 21, 25, 23, 36, 35, 42, 48
  • 3, 9, 9, 23, 25, 25, 36, 36, 42, 50
  • 3, 9, 11, 21, 22, 29, 34, 38, 42, 50
  • 3, 12, 12, 19, 27, 26, 35, 41, 40, 52
  • 3, 12, 14, 17, 27, 26, 35, 40, 42, 50
  • 5, 8, 13, 22, 25, 26, 36, 38, 43, 52
  • 5, 8, 17, 18, 21, 34, 31, 38, 48, 44
span 1 {1 1 1}