Structure 1008526

1008525 << 1008526 >> 1008527
Original COD entry Download CIF Download DOT

Citation: Birdwishtell, T L T; Klein, C L; Jeffries, T; Stevens, E D; O'Connor, C J (1991). Synthesis and crystal structures of the layered I-III-V Zintl phases, K~4~In~4~X~6~, where X=As, Sb. Journal of Materials Chemistry, 1, pp. 555-558.

Formula: In4 K4 Sb6

Chemical name: Tetrapotassium phyllo-hexaantimonidotetraindate

Cell parameters:

  • a = 15.288(5) Å
  • b = 7.544(1) Å
  • c = 16.790(3) Å
  • α = 90°
  • β = 90.54(2)°
  • γ = 90°

List type: interleaving

List: 2D

Combined 3D structure and graph

span 1 {1 1 1}
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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 2

Basis: (1;0;0 0;1;0)

Dimensionality: 2

Formula: In8 Sb12 (In2 Sb3)

Multiplicity: 1

Coordination sequences:

  • 3, 7, 9, 19, 23, 23, 31, 37, 41, 40
  • 3, 7, 9, 19, 23, 27, 32, 34, 41, 42
  • 3, 8, 9, 20, 20, 27, 28, 37, 42, 41
  • 3, 9, 11, 19, 21, 30, 32, 35, 44, 43
  • 3, 10, 11, 20, 24, 27, 35, 35, 40, 48
  • 3, 11, 13, 17, 20, 26, 34, 32, 47, 48
  • 4, 7, 12, 15, 26, 24, 31, 39, 38, 49
  • 4, 7, 16, 16, 23, 33, 29, 37, 41, 45
  • 5, 8, 12, 20, 24, 24, 34, 39, 40, 45
  • 5, 8, 16, 17, 20, 29, 30, 39, 42, 47
span 1 {1 1 1}

CIF datablock 1, entity 2 of 2

Basis: (1;0;0 0;1;0)

Dimensionality: 2

Formula: In8 Sb12 (In2 Sb3)

Multiplicity: 1

Coordination sequences:

  • 3, 7, 9, 19, 23, 23, 31, 37, 41, 40
  • 3, 7, 9, 19, 23, 27, 32, 34, 41, 42
  • 3, 8, 9, 20, 20, 27, 28, 37, 42, 41
  • 3, 9, 11, 19, 21, 30, 32, 35, 44, 43
  • 3, 10, 11, 20, 24, 27, 35, 35, 40, 48
  • 3, 11, 13, 17, 20, 26, 34, 32, 47, 48
  • 4, 7, 12, 15, 26, 24, 31, 39, 38, 49
  • 4, 7, 16, 16, 23, 33, 29, 37, 41, 45
  • 5, 8, 12, 20, 24, 24, 34, 39, 40, 45
  • 5, 8, 16, 17, 20, 29, 30, 39, 42, 47
span 1 {1 1 1}