Structure 1100850

1100783 << 1100850 >> 1100878
Original COD entry Download CIF Download DOT

Citation: Ghosh, Sundargopal; Fehlner, Thomas P.; Beatty, Alicia M.; Noll, Bruce C. (2005). Insertion of B-X (X = Cl, SMe~2~) Moieties into Ruthenaborane Frameworks: Synthesis and Characterization of (\h^5^-C~5~Me~5~Ru)~2~(\m-H)B~4~H~m~Cl~n~, (m, n = 4, 3; 5, 2; 7, 2), closo-1-(SMe~2~)-2,3-(\h^5^-C~5~Me~5~Ru)~2~(\m~3~-H)B~5~HCl~3~, and closo-2,3-(\h^5^-C~5~Me~5~Ru)~2~B~6~H~3~Cl~3~. Organometallics, 24, pp. 2473-2480.

Formula: C24.5 H43.84 B5 Cl3 Ru2 S

Cell parameters:

  • a = 22.027(3) Å
  • b = 12.4145(14) Å
  • c = 23.813(3) Å
  • α = 90.00°
  • β = 90.00°
  • γ = 90.00°

List type: interleaving

List: 1D

Combined 3D structure and graph

span 1 {1 1 1}
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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 8, entity 9 of 4

Basis: (0;1;0)

Dimensionality: 1

Formula: C10 (C)

Multiplicity: 1

Coordination sequences:

  • 2, 2, 2, 2, 2, 2, 2, 2, 2, 2
span 1 {1 1 1}

CIF datablock 9, entity 10 of 4

Basis: (0;1;0)

Dimensionality: 1

Formula: C10 (C)

Multiplicity: 1

Coordination sequences:

  • 2, 2, 2, 2, 2, 2, 2, 2, 2, 2
span 1 {1 1 1}

CIF datablock 10, entity 11 of 4

Basis: (0;1;0)

Dimensionality: 1

Formula: C10 (C)

Multiplicity: 1

Coordination sequences:

  • 2, 2, 2, 2, 2, 2, 2, 2, 2, 2
span 1 {1 1 1}

CIF datablock 11, entity 12 of 4

Basis: (0;1;0)

Dimensionality: 1

Formula: C10 (C)

Multiplicity: 1

Coordination sequences:

  • 2, 2, 2, 2, 2, 2, 2, 2, 2, 2
span 1 {1 1 1}