Structure 1508014

1508013 << 1508014 >> 1508026

Citation: Ding, Nan; Kanatzidis, Mercouri G. (2010). Selective incarceration of caesium ions by Venus flytrap action of a flexible framework sulfide.. Nature chemistry, 2, pp. 187-191.

Formula: Cs2 Ga2 S7 Sb2

Chemical name: ?

Cell parameters:

a = 15.591(3) Å
b = 9.1815(18) Å
c = 12.575(3) Å

α = 90.00°
β = 114.26(3)°
γ = 90.00°

List type: interleaving

List: 2D

Molecules

CIF datablock 0, entity 1 of 2

Basis: (0;1;0 0;0;1)

Dimensionality: 2

Formula: Ga4 S14 Sb6 (Ga2 S7 Sb3)

Multiplicity: 1

Coordination sequences:

2, 5, 5, 12, 13, 23, 23, 24, 31, 32
2, 5, 6, 15, 13, 20, 26, 27, 31, 29
2, 6, 5, 10, 14, 23, 22, 27, 32, 35
2, 7, 6, 10, 14, 21, 26, 27, 34, 33
2, 7, 7, 14, 13, 20, 21, 37, 31, 39
3, 3, 9, 9, 18, 21, 23, 27, 27, 39
3, 8, 8, 14, 14, 22, 21, 38, 30, 46
3, 9, 10, 13, 17, 23, 28, 30, 43, 35
4, 5, 11, 10, 17, 23, 27, 29, 28, 48
5, 5, 9, 11, 17, 20, 31, 28, 33, 43
5, 7, 13, 13, 18, 19, 29, 31, 43, 42
5, 9, 11, 15, 16, 23, 27, 37, 37, 43

span 1 {1 1 1}

highlight edges

CIF datablock 1, entity 2 of 2