Structure 1509994

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Citation: Seff, K.; Kim, Y. (1987). Silver ions in zeolite A are reduced by H2 only at high temperatures when 8-rings are blocked by Cs+. Crystal structures of dehydrated Ag9 Cs3-A treated with H2 at 23, 310, and 470 C. Bulletin of the Korean Chemical Society, 8, pp. 69-72.

Formula: Ag9 Al12 Cs2.9 O48 Si12

Chemical name: Ag9 Cs2.9 (Al12 Si12 O48)

Cell parameters:

  • a = 12.288 Å
  • b = 12.288 Å
  • c = 12.288 Å
  • α = 90°
  • β = 90°
  • γ = 90°

List type: noninterleaving

List: 3D

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Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 1

Basis: (1;0;0 0;1;0 0;0;1)

Dimensionality: 3

Formula: Ag14 Al24 O48 Si24 (Ag7 Al12 O24 Si12)

Multiplicity: 1

Coordination sequences:

  • 4, 8, 22, 42, 78, 111, 158, 207, 304, 362
  • 4, 10, 40, 68, 88, 111, 200, 269, 328, 412
  • 5, 10, 28, 57, 83, 109, 168, 257, 312, 390
  • 5, 17, 36, 57, 81, 126, 182, 244, 332, 423
  • 7, 22, 40, 64, 89, 144, 194, 270, 333, 458
  • 8, 33, 60, 52, 72, 157, 218, 237, 316, 488
  • 12, 30, 49, 66, 105, 150, 213, 273, 396, 453
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