Structure 1516509

1516508 << 1516509 >> 1516510
Original COD entry Download CIF Download DOT

Citation: Duyker, S. G.; Halder, G. J.; Southon, P. D.; Price, D. J.; Edwards, A. J.; Peterson, V. K.; Kepert, C. J. (2014). Topotactic structural conversion and hydration-dependent thermal expansion in robust LnMIII(CN)6·nH2O and flexible ALnFeII(CN)6·nH2O frameworks (A = Li, Na, K; Ln = La--Lu, Y; M = Co, Fe; 0 ≤ n ≤ 5). Chemical Science, 5, pp. 3409-.

Formula: C6 Fe K La N6

Chemical name: potassium lanthanum(III) hexacyanidoferrate(II)

Cell parameters:

  • a = 7.1852(10) Å
  • b = 7.1852(10) Å
  • c = 12.238(4) Å
  • α = 90.00°
  • β = 90.00°
  • γ = 120.00°

List type: noninterleaving

List: 3D

Combined 3D structure and graph

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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 1

Basis: (1;0;0 0;1;0 0;0;1)

Dimensionality: 3

Formula: C12 Fe2 La2 N12 (C6 Fe La N6)

Multiplicity: 1

Coordination sequences:

  • 2, 6, 10, 10, 30, 46, 34, 72, 114, 84
  • 2, 6, 10, 10, 30, 46, 36, 82, 114, 74
  • 6, 6, 6, 30, 30, 18, 78, 78, 42, 174
  • 6, 6, 6, 30, 30, 20, 90, 90, 42, 162
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