Structure 1531542

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Original COD entry Download CIF Download DOT

Citation: Huang, J.; Wang, X.-Q.; Liu, L.-M.; Jacobson, A.J. (2002). Synthesis and characterization of an open framework vanadium silicate (VSH-16Na). Solid State Sciences, 4, pp. 1193-1198.

Formula: H2 Na3 O12 Si4 V

Chemical name: Na3 (V Si4 O11) (H2 O)

Cell parameters:

  • a = 7.5238 Å
  • b = 8.755 Å
  • c = 9.055 Å
  • α = 62.486°
  • β = 83.998°
  • γ = 88.692°

List type: noninterleaving

List: 3D

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Molecules

CIF datablock 0, entity 1 of 1

Basis: (1;0;0 0;1;0 0;0;1)

Dimensionality: 3

Formula: O22 Si8 V2 (O11 Si4 V)

Multiplicity: 1

Coordination sequences:

  • 2, 6, 5, 17, 14, 41, 28, 76, 50, 137
  • 2, 6, 6, 20, 16, 46, 30, 80, 54, 148
  • 2, 6, 6, 21, 17, 44, 28, 84, 58, 146
  • 2, 8, 7, 19, 15, 48, 33, 84, 51, 138
  • 2, 8, 7, 20, 15, 44, 32, 86, 53, 143
  • 2, 8, 8, 22, 16, 48, 34, 90, 56, 150
  • 4, 4, 13, 11, 34, 23, 63, 42, 114, 71
  • 4, 4, 15, 12, 32, 24, 70, 45, 122, 73
  • 6, 6, 16, 12, 38, 28, 74, 44, 118, 76
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