Structure 1545022

1544921 << 1545022 >> 1545023

Citation: Masquelier, C; d Yvoire, F.; Rodier, N. (1991). Crystal structure of the sodium ion conductor alpha-Na7Fe3(P2O7)4: evidence for a long-range ordering of the Na+ ions. Journal of Solid State Chemistry, 95, pp. 156-167.

Formula: Fe3 Na7 O28 P8

Cell parameters:

a = 9.506(3) Å
b = 8.333(2) Å
c = 27.732(5) Å

α = 90.°
β = 93.33(3)°
γ = 90.°

List type: noninterleaving

List: 3D

Combined 3D structure and graph

JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 1

Basis: (1;0;0 0;1;0 0;0;1)

Dimensionality: 3

Formula: Fe12 O112 P32 (Fe3 O28 P8)

Multiplicity: 1

Coordination sequences:

1, 3, 3, 12, 10, 29, 17, 64, 48, 132
1, 3, 3, 12, 10, 30, 20, 69, 45, 126
1, 3, 3, 12, 11, 34, 21, 70, 46, 127
2, 6, 3, 14, 14, 38, 20, 78, 57, 150
2, 6, 4, 19, 17, 44, 23, 83, 58, 150
2, 8, 6, 18, 12, 42, 31, 94, 52, 150
2, 8, 6, 18, 12, 43, 33, 96, 47, 140
2, 8, 6, 19, 15, 50, 32, 93, 49, 141
2, 8, 7, 20, 11, 43, 35, 100, 48, 147
2, 8, 7, 21, 14, 50, 34, 95, 47, 147
2, 8, 7, 21, 15, 52, 36, 97, 46, 146
2, 8, 7, 22, 15, 49, 32, 93, 48, 141
2, 8, 8, 25, 16, 53, 34, 96, 49, 147
2, 8, 8, 25, 16, 53, 34, 98, 52, 153
4, 3, 12, 10, 29, 17, 64, 48, 132, 60
4, 3, 12, 10, 30, 20, 69, 45, 126, 62
4, 3, 12, 11, 34, 21, 70, 46, 127, 57
4, 4, 17, 13, 37, 23, 75, 48, 133, 58
6, 6, 16, 8, 34, 30, 84, 38, 120, 76
6, 6, 17, 11, 41, 30, 82, 36, 114, 77

span 1 {1 1 1}

highlight edges