Structure 1549739

1549722 << 1549739 >> 1549740
Original COD entry Download CIF Download DOT

Citation: Tahmouresilerd, Babak; Larson, Patrick J.; Unruh, Daniel K.; Cozzolino, Anthony F. (2018). Make room for iodine: systematic pore tuning of multivariate metal--organic frameworks for the catalytic oxidation of hydroquinones using hypervalent iodine. Catalysis Science & Technology, 8, pp. 4349-.

Formula: C8 H4.19 Al I0.82 O5

Cell parameters:

  • a = 16.501(4) Å
  • b = 6.6194(18) Å
  • c = 13.210(4) Å
  • α = 90°
  • β = 90°
  • γ = 90°

List type: noninterleaving

List: 3D

Combined 3D structure and graph

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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 1

Basis: (1;0;0 0;1;0 0;0;1)

Dimensionality: 3

Formula: C48 H36 Al4 I48 O20 (C12 H9 Al I12 O5)

Multiplicity: 1

Coordination sequences:

  • 1, 2, 10, 10, 16, 32, 98, 130, 152, 160
  • 2, 7, 11, 26, 45, 87, 110, 152, 167, 221
  • 2, 7, 18, 33, 47, 69, 89, 110, 128, 206
  • 3, 6, 23, 35, 52, 64, 122, 156, 185, 203
  • 3, 9, 20, 33, 45, 74, 86, 110, 146, 202
  • 3, 10, 10, 16, 32, 98, 130, 152, 160, 216
  • 5, 13, 26, 40, 61, 79, 100, 124, 176, 271
  • 5, 16, 27, 46, 54, 79, 103, 160, 180, 229
  • 6, 8, 14, 24, 70, 108, 142, 144, 198, 228
  • 6, 13, 24, 44, 52, 81, 101, 113, 159, 211
  • 6, 14, 27, 39, 60, 83, 96, 129, 188, 256
  • 8, 15, 27, 41, 58, 81, 102, 134, 156, 212
  • 9, 16, 27, 44, 59, 78, 107, 132, 156, 216
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