Structure 1549740

1549739 << 1549740 >> 1549764
Original COD entry Download CIF Download DOT

Citation: Tahmouresilerd, Babak; Larson, Patrick J.; Unruh, Daniel K.; Cozzolino, Anthony F. (2018). Make room for iodine: systematic pore tuning of multivariate metal--organic frameworks for the catalytic oxidation of hydroquinones using hypervalent iodine. Catalysis Science & Technology, 8, pp. 4349-.

Formula: C8 H4.3 Al I0.7 O5.25

Cell parameters:

  • a = 17.107(11) Å
  • b = 6.622(4) Å
  • c = 12.229(8) Å
  • α = 90°
  • β = 90°
  • γ = 90°

List type: noninterleaving

List: 3D

Combined 3D structure and graph

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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 1

Basis: (1;0;0 0;1;0 0;0;1)

Dimensionality: 3

Formula: C48 H36 Al4 I32 O20 (C12 H9 Al I8 O5)

Multiplicity: 1

Coordination sequences:

  • 1, 2, 10, 10, 16, 32, 86, 110, 120, 144
  • 2, 6, 14, 28, 44, 66, 81, 102, 121, 199
  • 2, 7, 11, 24, 39, 75, 97, 131, 156, 208
  • 2, 8, 19, 30, 45, 69, 82, 105, 139, 192
  • 3, 6, 21, 29, 44, 62, 118, 140, 153, 192
  • 3, 10, 10, 16, 32, 86, 110, 120, 144, 220
  • 5, 10, 21, 41, 48, 71, 97, 107, 156, 194
  • 5, 11, 20, 34, 59, 79, 88, 115, 165, 253
  • 5, 14, 21, 38, 52, 83, 101, 138, 167, 211
  • 6, 8, 14, 24, 62, 92, 114, 128, 198, 232
  • 6, 13, 22, 38, 60, 80, 90, 120, 180, 248
  • 6, 15, 27, 41, 55, 72, 105, 128, 147, 203
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