Structure 1560109

1560108 << 1560109 >> 1560110
Original COD entry Download CIF Download DOT

Citation: Lee, Jie Yie; Ling, Sanliang; Argent, Stephen P.; Senn, Mark S.; Ca\~nadillas-Delgado, Laura; Cliffe, Matthew J. (2021). Controlling multiple orderings in metal thiocyanate molecular perovskites Ax{Ni[Bi(SCN)6]}. Chemical Science, 12, pp. 3516-3525.

Formula: C0.92 Bi0.15 N1.25 Ni0.17 S0.86

Chemical name: triguanidinium hexanickel(II) pentahexathiocyanatobismuthate

Cell parameters:

  • a = 12.12528(2) Å
  • b = 12.12528(2) Å
  • c = 12.12528(2) Å
  • α = 90.000°
  • β = 90.000°
  • γ = 90.000°

List type: noninterleaving

List: 3D

Combined 3D structure and graph

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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 1

Basis: (1;0;0 0;1;0 0;0;1)

Dimensionality: 3

Formula: C24 Bi4 N24 Ni4 S24 (C6 Bi N6 Ni S6)

Multiplicity: 1

Coordination sequences:

  • 2, 2, 10, 10, 10, 10, 50, 46, 42, 26
  • 2, 6, 6, 10, 10, 30, 30, 46, 34, 78
  • 6, 6, 6, 6, 30, 30, 30, 18, 78, 78
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