Structure 1561052

1561042 << 1561052 >> 1561053
Original COD entry Download CIF Download DOT

Citation: Zhang, Shi-Yuan; Yang, Yuan-Yuan; Zheng, Yue-Qing; Zhu, Hong-Lin (2018). Ag-doped Co3O4 catalyst derived from heterometallic MOF for syngas production by electrocatalytic reduction of CO2 in water. Journal of Solid State Chemistry, 263, pp. 44-51.

Formula: C54 H30 Ag6 Co3 N12 O24

Cell parameters:

  • a = 16.064(3) Å
  • b = 25.821(5) Å
  • c = 13.787(3) Å
  • α = 90°
  • β = 90°
  • γ = 90°

List type: interleaving

List: 2D

Combined 3D structure and graph

span 1 {1 1 1}
Ctrl-click to select multiple nodes

JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 4

Basis: (1;0;0 0;0;1)

Dimensionality: 2

Formula: C56 H24 Ag8 Co4 N8 O32 (C14 H6 Ag2 Co N2 O8)

Multiplicity: 1

Coordination sequences:

  • 1, 2, 4, 3, 5, 6, 12, 17, 26, 32
  • 1, 2, 4, 5, 6, 10, 16, 21, 26, 39
  • 1, 2, 4, 5, 7, 10, 12, 20, 25, 36
  • 2, 5, 8, 16, 21, 26, 29, 33, 39, 41
  • 2, 5, 9, 16, 25, 33, 32, 32, 42, 51
  • 2, 7, 10, 17, 20, 21, 33, 46, 54, 56
  • 3, 4, 3, 5, 6, 12, 17, 26, 32, 48
  • 3, 4, 5, 6, 10, 16, 21, 26, 39, 45
  • 3, 4, 5, 7, 10, 12, 20, 25, 36, 44
  • 3, 4, 10, 15, 21, 27, 32, 39, 44, 57
  • 3, 5, 11, 12, 19, 20, 30, 37, 39, 52
  • 3, 6, 8, 11, 16, 21, 26, 39, 45, 53
  • 3, 6, 9, 11, 12, 20, 25, 36, 44, 58
  • 3, 9, 11, 12, 15, 19, 27, 40, 56, 56
  • 3, 10, 12, 16, 21, 26, 35, 38, 51, 58
  • 4, 7, 11, 19, 29, 30, 32, 36, 39, 50
  • 6, 10, 14, 16, 17, 26, 34, 50, 59, 52
span 1 {1 1 1}

CIF datablock 1, entity 2 of 4

Basis: (1;0;0 0;0;1)

Dimensionality: 2

Formula: C56 H24 Ag8 Co4 N8 O32 (C14 H6 Ag2 Co N2 O8)

Multiplicity: 1

Coordination sequences:

  • 1, 2, 4, 3, 5, 6, 12, 17, 26, 32
  • 1, 2, 4, 5, 6, 10, 16, 21, 26, 39
  • 1, 2, 4, 5, 7, 10, 12, 20, 25, 36
  • 2, 5, 8, 16, 21, 26, 29, 33, 39, 41
  • 2, 5, 9, 16, 25, 33, 32, 32, 42, 51
  • 2, 7, 10, 17, 20, 21, 33, 46, 54, 56
  • 3, 4, 3, 5, 6, 12, 17, 26, 32, 48
  • 3, 4, 5, 6, 10, 16, 21, 26, 39, 45
  • 3, 4, 5, 7, 10, 12, 20, 25, 36, 44
  • 3, 4, 10, 15, 21, 27, 32, 39, 44, 57
  • 3, 5, 11, 12, 19, 20, 30, 37, 39, 52
  • 3, 6, 8, 11, 16, 21, 26, 39, 45, 53
  • 3, 6, 9, 11, 12, 20, 25, 36, 44, 58
  • 3, 9, 11, 12, 15, 19, 27, 40, 56, 56
  • 3, 10, 12, 16, 21, 26, 35, 38, 51, 58
  • 4, 7, 11, 19, 29, 30, 32, 36, 39, 50
  • 6, 10, 14, 16, 17, 26, 34, 50, 59, 52
span 1 {1 1 1}

CIF datablock 2, entity 3 of 4

Basis: (1;0;0 0;0;1)

Dimensionality: 2

Formula: C44 H28 Ag4 Co2 N12 O16 (C22 H14 Ag2 Co N6 O8)

Multiplicity: 1

span 1 {1 1 1}

CIF datablock 3, entity 4 of 4

Basis: (1;0;0 0;0;1)

Dimensionality: 2

Formula: C44 H28 Ag4 Co2 N12 O16 (C22 H14 Ag2 Co N6 O8)

Multiplicity: 1

span 1 {1 1 1}