Structure 1562759

1562758 << 1562759 >> 1562760
Original COD entry Download CIF Download DOT

Citation: Yao, Hua-Gang; Ji, Min; Ji, Shou-Hua; An, Yong-Lin (2013). Synthesis, structure and characterization of two new copper(І)-thioarsenates (ІІІ) constructed by the [AsS3]3− and CuSx units. Journal of Solid State Chemistry, 198, pp. 289-294.

Formula: As Cs Cu2 S3

Cell parameters:

  • a = 9.531(5) Å
  • b = 10.433(5) Å
  • c = 13.355(7) Å
  • α = 90.00°
  • β = 90.00°
  • γ = 90.00°

List type: interleaving

List: 2D

Combined 3D structure and graph

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Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 2

Basis: (1;0;0 0;1;0)

Dimensionality: 2

Formula: As4 Cu8 S12 (As Cu2 S3)

Multiplicity: 1

Coordination sequences:

  • 3, 7, 15, 21, 27, 31, 40, 44, 48, 59
  • 3, 9, 16, 21, 27, 34, 38, 47, 51, 59
  • 3, 12, 15, 24, 28, 37, 37, 50, 51, 58
  • 4, 8, 18, 20, 31, 32, 42, 45, 55, 56
  • 5, 11, 18, 21, 31, 33, 43, 44, 55, 57
  • 6, 11, 16, 25, 26, 37, 40, 48, 50, 61
span 1 {1 1 1}

CIF datablock 1, entity 2 of 2

Basis: (1;0;0 0;1;0)

Dimensionality: 2

Formula: As4 Cu8 S12 (As Cu2 S3)

Multiplicity: 1

Coordination sequences:

  • 3, 7, 15, 21, 27, 31, 40, 44, 48, 59
  • 3, 9, 16, 21, 27, 34, 38, 47, 51, 59
  • 3, 12, 15, 24, 28, 37, 37, 50, 51, 58
  • 4, 8, 18, 20, 31, 32, 42, 45, 55, 56
  • 5, 11, 18, 21, 31, 33, 43, 44, 55, 57
  • 6, 11, 16, 25, 26, 37, 40, 48, 50, 61
span 1 {1 1 1}