Structure 1565263

1565261 << 1565263 >> 1565283
Original COD entry Download CIF Download DOT

Citation: Balijapelly, Srikanth; Ghosh, Kartik; Chernatynskiy, Aleksandr V.; Choudhury, Amitava (2021). Discovery of an olivine-type lithium manganese thiophosphate, LiMnPS 4 , via a building block approach. Chemical Communications, 57, pp. 13182-13185.

Formula: Li Mn P S4

Cell parameters:

  • a = 12.540(3) Å
  • b = 7.6545(16) Å
  • c = 5.8345(12) Å
  • α = 90°
  • β = 90°
  • γ = 90°

List type: interleaving

List: 2D

Combined 3D structure and graph

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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 2

Basis: (0;1;0 0;0;1)

Dimensionality: 2

Formula: Mn2 P2 S8 (Mn P S4)

Multiplicity: 1

Coordination sequences:

  • 2, 7, 7, 21, 14, 33, 20, 44, 26, 57
  • 3, 10, 9, 24, 15, 36, 21, 46, 27, 58
  • 3, 12, 9, 22, 15, 34, 21, 48, 27, 60
  • 4, 4, 16, 12, 28, 18, 42, 24, 52, 30
  • 6, 6, 16, 12, 30, 18, 40, 24, 54, 30
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CIF datablock 1, entity 2 of 2

Basis: (0;1;0 0;0;1)

Dimensionality: 2

Formula: Mn2 P2 S8 (Mn P S4)

Multiplicity: 1

Coordination sequences:

  • 2, 7, 7, 21, 14, 33, 20, 44, 26, 57
  • 3, 10, 9, 24, 15, 36, 21, 46, 27, 58
  • 3, 12, 9, 22, 15, 34, 21, 48, 27, 60
  • 4, 4, 16, 12, 28, 18, 42, 24, 52, 30
  • 6, 6, 16, 12, 30, 18, 40, 24, 54, 30
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