Structure 1568978

1568977 << 1568978 >> 1568981
Original COD entry Download CIF Download DOT

Citation: Oberdorf, Kai; Hanft, Anna; Xie, Xiulan; Bickelhaupt, F. Matthias; Poater, Jordi; Lichtenberg, Crispin (2023). Insertion of CO2 and CS2 into Bi-N bonds enables catalyzed CH-activation and light-induced bismuthinidene transfer.. Chemical science, 14, pp. 5214-5219.

Formula: C52 H50 Bi3 F9 N4 O17 S3

Cell parameters:

  • a = 13.745(4) Å
  • b = 17.557(5) Å
  • c = 25.813(10) Å
  • α = 90°
  • β = 90°
  • γ = 90°

List type: interleaving

List: 1D

Combined 3D structure and graph

span 1 {1 1 1}
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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 2

Basis: (0;1;0)

Dimensionality: 1

Formula: C90 H74 Bi6 F12 N6 O26 S4 (C45 H37 Bi3 F6 N3 O13 S2)

Multiplicity: 1

span 1 {1 1 1}

CIF datablock 1, entity 2 of 2

Basis: (0;1;0)

Dimensionality: 1

Formula: C90 H74 Bi6 F12 N6 O26 S4 (C45 H37 Bi3 F6 N3 O13 S2)

Multiplicity: 1

span 1 {1 1 1}