Structure 2001192

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Citation: Guesdon, A.; Borel, M. M.; Grandin, A.; Leclaire, A.; Raveau, B. (1993). Structure of Tl~2~Mo~2~P~2~O~11~. Acta Crystallographica Section C, 49, pp. 1877-1879.

Formula: Mo2 O11 P2 Tl2

Cell parameters:

  • a = 9.9450(10) Å
  • b = 10.1560(10) Å
  • c = 9.974(2) Å
  • α = 90°
  • β = 97.640(10)°
  • γ = 90°

List type: noninterleaving

List: 3D

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Molecules

CIF datablock 0, entity 1 of 1

Basis: (1;0;0 0;1;0 0;0;1)

Dimensionality: 3

Formula: Mo8 O44 P8 (Mo2 O11 P2)

Multiplicity: 1

Coordination sequences:

  • 1, 5, 5, 15, 11, 45, 25, 73, 43, 153
  • 2, 8, 6, 22, 15, 50, 31, 104, 49, 155
  • 2, 8, 7, 25, 15, 53, 31, 103, 55, 163
  • 2, 8, 7, 25, 16, 54, 31, 107, 57, 166
  • 2, 10, 6, 16, 12, 52, 30, 82, 46, 176
  • 4, 4, 19, 12, 33, 22, 91, 45, 123, 67
  • 6, 5, 15, 11, 45, 25, 73, 43, 153, 69
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