Structure 2002637

2002636 << 2002637 >> 2002638
Original COD entry Download CIF Download DOT

Citation: Osterloh, D; Mueller-Buschbaum, Hk (1994). Das erste Oxocuprat/-Arsenat mit Kupfer in gemischter Valenz: Cu (Mg27.56 Cu0.44) Cu (As O4)3. Zeitschrift fuer Naturforschung, Teil B. Anorganische Chemie,Organische Chemie (42,1987-), 49, pp. 589-592.

Formula: As3 Cu2.44 Mg2.56 O12

Chemical name: Copper magnesium arsenate(V) (2.44/2.65/3)

Cell parameters:

  • a = 11.897(7) Å
  • b = 12.855(2) Å
  • c = 6.688(4) Å
  • α = 90°
  • β = 113.06(4)°
  • γ = 90°

List type: noninterleaving

List: 3D

Combined 3D structure and graph

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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 1

Basis: (1;0;0 0;1;0 0;0;1)

Dimensionality: 3

Formula: As12 Cu20 Mg12 O48 (As3 Cu5 Mg3 O12)

Multiplicity: 1

Coordination sequences:

  • 3, 17, 46, 99, 184, 278, 418, 576, 753, 944
  • 4, 15, 46, 96, 179, 290, 431, 571, 758, 974
  • 4, 16, 49, 102, 178, 294, 426, 569, 764, 965
  • 4, 18, 38, 94, 174, 272, 405, 570, 751, 937
  • 4, 18, 41, 101, 186, 284, 431, 577, 773, 961
  • 5, 11, 31, 62, 134, 219, 331, 488, 663, 825
  • 5, 11, 35, 79, 154, 237, 375, 514, 691, 888
  • 5, 15, 51, 96, 179, 294, 404, 573, 739, 969
  • 5, 16, 57, 105, 195, 315, 442, 598, 780, 1011
  • 5, 17, 39, 99, 178, 284, 411, 583, 764, 952
  • 8, 29, 70, 128, 212, 326, 451, 610, 801, 1012
  • 8, 36, 80, 150, 246, 374, 516, 662, 890, 1110
  • 10, 25, 56, 128, 219, 311, 480, 645, 815, 1040
  • 10, 26, 62, 135, 222, 341, 488, 654, 840, 1059
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