Structure 2006286

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Original COD entry Download CIF Download DOT

Citation: Zavalij, Peter Y.; Chirayil, Thomas; Whittingham, M. Stanley (1997). Layered Tetramethylammonium Vanadium Oxide [N(CH~3~)~4~]V~3~O~7~ by X-ray Rietveld Refinement. Acta Crystallographica Section C, 53, pp. 879-881.

Formula: C4 H12 N O7 V3

Chemical name: tetramethylammonium trivanadius heptaoxide

Cell parameters:

  • a = 18.4783(5) Å
  • b = 6.5523(2) Å
  • c = 8.4268(3) Å
  • α = 90°
  • β = 91.132(2)°
  • γ = 90°

List type: interleaving

List: 2D

Combined 3D structure and graph

span 1 {1 1 1}
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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 2

Basis: (0;1;0 0;0;1)

Dimensionality: 2

Formula: O14 V6 (O7 V3)

Multiplicity: 1

Coordination sequences:

  • 1, 3, 5, 22, 24, 32, 27, 47, 42, 66
  • 1, 6, 10, 16, 22, 24, 46, 36, 50, 48
  • 1, 6, 11, 18, 16, 35, 30, 51, 40, 60
  • 2, 9, 14, 29, 26, 38, 31, 60, 51, 66
  • 3, 12, 12, 21, 25, 32, 50, 40, 53, 55
  • 3, 12, 13, 25, 27, 38, 39, 53, 42, 71
  • 4, 5, 22, 24, 32, 27, 47, 42, 66, 52
  • 7, 10, 16, 22, 24, 46, 36, 50, 48, 64
  • 7, 11, 18, 16, 35, 30, 51, 40, 60, 53
span 1 {1 1 1}

CIF datablock 1, entity 2 of 2

Basis: (0;1;0 0;0;1)

Dimensionality: 2

Formula: O14 V6 (O7 V3)

Multiplicity: 1

Coordination sequences:

  • 1, 3, 5, 22, 24, 32, 27, 47, 42, 66
  • 1, 6, 10, 16, 22, 24, 46, 36, 50, 48
  • 1, 6, 11, 18, 16, 35, 30, 51, 40, 60
  • 2, 9, 14, 29, 26, 38, 31, 60, 51, 66
  • 3, 12, 12, 21, 25, 32, 50, 40, 53, 55
  • 3, 12, 13, 25, 27, 38, 39, 53, 42, 71
  • 4, 5, 22, 24, 32, 27, 47, 42, 66, 52
  • 7, 10, 16, 22, 24, 46, 36, 50, 48, 64
  • 7, 11, 18, 16, 35, 30, 51, 40, 60, 53
span 1 {1 1 1}