Structure 2011819

2011816 << 2011819 >> 2011820
Original COD entry Download CIF Download DOT

Citation: Kim, Youngmee; Kim, Sung-Jin; Nam, Wonwoo (2001). A ferric-cyanide-bridged one-dimensional dirhodium complex with (18-crown-6)potassium cations. Acta Crystallographica Section C, 57, pp. 266-268.

Formula: C70 H116 Fe K3 N6 O38 Rh2

Chemical name: [{K(18-crown-6-ether)(H~2~O)}~2~{K(18-crown-6-ether)(H~2~O)~2~}][Rh~2~(O~2~CC~6~H~5~)~4~Fe(CN)~6~]8H~2~O(18-crown-6-ether = 1,4,7,10,13,16-hexaoxacyclooctadecane)

Cell parameters:

  • a = 16.0884(4) Å
  • b = 23.1083(5) Å
  • c = 25.8233(6) Å
  • α = 90.00°
  • β = 104.0900(10)°
  • γ = 90.00°

List type: interleaving

List: 1D

Combined 3D structure and graph

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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 2

Basis: (0;0;1)

Dimensionality: 1

Formula: C68 H40 Fe2 N12 O16 Rh4 (C34 H20 Fe N6 O8 Rh2)

Multiplicity: 1

span 1 {1 1 1}

CIF datablock 1, entity 2 of 2

Basis: (0;0;1)

Dimensionality: 1

Formula: C68 H40 Fe2 N12 O16 Rh4 (C34 H20 Fe N6 O8 Rh2)

Multiplicity: 1

span 1 {1 1 1}