Structure 2014319

2014311 << 2014319 >> 2014321
Original COD entry Download CIF Download DOT

Citation: Rohm, Henning W.; K\"ockerling, Martin (2006). Cation distribution in the zirconium chloride cluster phase Cs[(Zr~6~C)Cl~15~]. Acta Crystallographica Section C, 62, pp. i19-i20.

Formula: C Cl15 Cs Zr6

Chemical name: Poly[caesium[[\m~4~-carbido-dodecakis-\m~2~-chloro-hexazirconium]-tri-\m~2~-chloro]]

Cell parameters:

  • a = 18.513(2) Å
  • b = 13.9160(10) Å
  • c = 9.6383(7) Å
  • α = 90.00°
  • β = 90.00°
  • γ = 90.00°

List type: noninterleaving

List: 3D

Combined 3D structure and graph

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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 1

Basis: (1;0;0 0;1;0 0;0;1)

Dimensionality: 3

Formula: C4 Cl60 Zr24 (C Cl15 Zr6)

Multiplicity: 1

Coordination sequences:

  • 2, 13, 11, 22, 61, 56, 61, 170, 189, 201
  • 2, 13, 11, 22, 61, 59, 66, 181, 209, 194
  • 2, 13, 11, 22, 62, 55, 61, 170, 189, 201
  • 2, 13, 11, 22, 62, 56, 64, 167, 193, 216
  • 2, 13, 11, 22, 62, 56, 68, 170, 186, 216
  • 2, 13, 11, 22, 62, 58, 66, 181, 209, 190
  • 2, 13, 11, 22, 62, 59, 80, 195, 191, 218
  • 2, 18, 26, 10, 62, 88, 46, 166, 264, 182
  • 2, 18, 26, 10, 68, 102, 50, 190, 315, 173
  • 2, 18, 26, 10, 74, 118, 58, 186, 310, 250
  • 6, 18, 6, 54, 74, 22, 138, 228, 122, 332
  • 6, 18, 6, 54, 76, 26, 162, 238, 130, 306
  • 10, 14, 14, 50, 62, 46, 138, 194, 164, 354
  • 10, 14, 14, 50, 62, 53, 135, 194, 191, 327
  • 10, 14, 14, 50, 64, 56, 159, 216, 175, 317
  • 10, 14, 14, 50, 64, 66, 152, 186, 220, 318
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