Structure 2014504

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Citation: Feazell, Rodney P.; Carson, Cody E.; Klausmeyer, Kevin K. (2004). Self-assembly of a mixed-ligand silver-based coordination polymer. Acta Crystallographica Section C, 60, pp. m598-m600.

Formula: C116 H116 Ag4 B4 F16 N16 P6

Chemical name: catena-poly[[[acetonitrilesilver(I)]-di-\m-4-[N-(diphenylphosphino)aminomethyl]pyridine-\k^2^N^1^:P;\k^2^P:N^1^-[acetonitrilesilver(I)]-\m~3~-4-[N,N-bis(diphenylphosphino)aminomethyl]pyridine-\k^3^N^1^:P:P'-bis[acetonitrilesilver(I)(Ag---Ag)]-\m~3~-4-[N,N-bis(diphenylphosphino)aminomethyl]pyridine-\k^3^P:P':N^1^]tetrakis(tetrafluoroborate) acetonitrile trisolvate]

Cell parameters:

  • a = 13.2233(8) Å
  • b = 14.6535(11) Å
  • c = 16.7275(12) Å
  • α = 97.085(2)°
  • β = 104.690(2)°
  • γ = 101.691(3)°

List type: noninterleaving

List: 1D

Combined 3D structure and graph

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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 1

Basis: (0;1;1)

Dimensionality: 1

Formula: C104 H98 Ag4 N12 P6 (C52 H49 Ag2 N6 P3)

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