Structure 2015027

2015026 << 2015027 >> 2015028
Original COD entry Download CIF Download DOT

Citation: Gall, P.; Gougeon, P. (2005). La~5~Mo~6~O~21~: a novel ternary reduced molybdenum oxide containing {Mo^IV^}~3~ clusters and isolated Mo^V^ centres. Acta Crystallographica Section C, 61, pp. i69-i70.

Formula: La5 Mo6 O21

Chemical name: pentalanthanum hexamolybdenum henicosaoxide

Cell parameters:

  • a = 5.71550(5) Å
  • b = 11.24290(10) Å
  • c = 25.2146(2) Å
  • α = 90.00°
  • β = 90.00°
  • γ = 90.00°

List type: noninterleaving

List: 3D

Combined 3D structure and graph

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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 1

Basis: (1;0;0 0;1;0 0;0;1)

Dimensionality: 3

Formula: La20 Mo24 O84 (La5 Mo6 O21)

Multiplicity: 1

Coordination sequences:

  • 3, 22, 64, 158, 269, 402, 587, 812, 1110, 1459
  • 3, 23, 58, 146, 239, 404, 575, 815, 1055, 1453
  • 3, 23, 64, 154, 273, 410, 606, 841, 1082, 1419
  • 3, 28, 85, 161, 250, 422, 655, 864, 1156, 1427
  • 3, 29, 86, 151, 241, 426, 661, 863, 1109, 1395
  • 3, 29, 89, 172, 283, 434, 660, 941, 1162, 1453
  • 3, 33, 91, 156, 264, 456, 679, 884, 1159, 1454
  • 4, 27, 68, 162, 279, 398, 567, 831, 1115, 1404
  • 4, 27, 70, 180, 293, 444, 625, 869, 1165, 1478
  • 4, 30, 83, 187, 314, 470, 660, 914, 1224, 1557
  • 4, 31, 82, 187, 310, 471, 652, 913, 1208, 1567
  • 4, 31, 82, 191, 295, 435, 641, 915, 1159, 1479
  • 4, 32, 85, 189, 295, 433, 682, 951, 1223, 1480
  • 4, 33, 82, 165, 271, 463, 666, 871, 1197, 1468
  • 4, 33, 84, 194, 304, 443, 653, 923, 1174, 1504
  • 4, 35, 79, 165, 277, 455, 661, 869, 1184, 1460
  • 4, 35, 81, 197, 283, 432, 678, 939, 1219, 1468
  • 4, 36, 81, 175, 295, 458, 676, 890, 1151, 1537
  • 4, 36, 82, 173, 300, 453, 675, 882, 1155, 1516
  • 4, 37, 97, 184, 304, 475, 705, 937, 1190, 1539
  • 4, 40, 100, 173, 300, 486, 720, 929, 1201, 1477
  • 9, 23, 79, 163, 290, 437, 601, 844, 1180, 1460
  • 9, 23, 81, 163, 285, 438, 604, 846, 1185, 1458
  • 10, 41, 108, 200, 317, 503, 724, 1005, 1278, 1564
  • 11, 34, 121, 218, 323, 487, 764, 1027, 1272, 1550
  • 11, 42, 96, 196, 326, 488, 704, 921, 1235, 1625
  • 11, 42, 116, 185, 354, 521, 715, 959, 1297, 1634
  • 11, 51, 118, 210, 354, 510, 777, 993, 1246, 1596
  • 12, 61, 128, 189, 350, 562, 783, 1009, 1281, 1566
  • 13, 33, 109, 212, 321, 503, 698, 956, 1238, 1584
  • 18, 59, 127, 216, 358, 577, 778, 1063, 1320, 1591
  • 18, 61, 120, 220, 357, 582, 778, 1012, 1328, 1642
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