Structure 2018404

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Citation: Jia, Li-Na; Hou, Lei (2012). Poly[tetraamminecopper(II) bis[tris(\m~2~-cyanido-\k^2^C,N)dicuprate(I)]]: a unique Cu^I^--Cu^II^ mixed-valence complex containing anionic cuprous cyanide layers and [Cu(NH~3~)~4~]^2+^ cations. Acta Crystallographica Section C, 68, pp. m45-m47.

Formula: C6 H12 Cu5 N10

Chemical name: Poly[tetraamminecopper(II) bis[tris(\m~2~-cyanido-\k^2^<i>C</i>,<i>N</i>)dicuprate(I)]]

Cell parameters:

  • a = 7.6501(9) Å
  • b = 8.9083(10) Å
  • c = 13.2509(12) Å
  • α = 90.00°
  • β = 123.086(5)°
  • γ = 90.00°

List type: interleaving

List: 2D

Combined 3D structure and graph

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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 2, entity 3 of 2

Basis: (1;0;0.5 0;1;0)

Dimensionality: 2

Formula: C6 Cu4 N6 (C3 Cu2 N3)

Coordination sequences:

  • 2, 3, 4, 4, 6, 8, 8, 12, 14, 11
  • 3, 3, 3, 6, 6, 6, 12, 12, 9, 15
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CIF datablock 3, entity 4 of 2

Basis: (1;0;0.5 0;1;0)

Dimensionality: 2

Formula: C6 Cu4 N6 (C3 Cu2 N3)

Coordination sequences:

  • 2, 3, 4, 4, 6, 8, 8, 12, 14, 11
  • 3, 3, 3, 6, 6, 6, 12, 12, 9, 15
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