Structure 2018708

2018707 << 2018708 >> 2018712
Original COD entry Download CIF Download DOT

Citation: Dal Bo, Fabrice; Hatert, Fr\'ed\'eric (2012). Fe~6.67~(PO~4~)~5.35~(HPO~4~)~0.65~ and Fe~6.23~(PO~4~)~4.45~(HPO~4~)~1.55~: two new mixed-valence iron phosphates. Acta Crystallographica Section C, 68, pp. i83-i85.

Formula: Fe6.23 H1.55 O24 P6

Chemical name: Heptairon tetraphosphate bis(hydrogen phosphate)

Cell parameters:

  • a = 6.3445(2) Å
  • b = 7.9353(3) Å
  • c = 9.2829(3) Å
  • α = 105.303(3)°
  • β = 108.176(3)°
  • γ = 101.700(3)°

List type: noninterleaving

List: 3D

Combined 3D structure and graph

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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 1

Basis: (1;0;0 0;1;0 0;0;1)

Dimensionality: 3

Formula: Fe7 O24 P6 (Fe7 O24 P6)

Multiplicity: 1

Coordination sequences:

  • 2, 8, 12, 37, 37, 97, 76, 179, 135, 311
  • 2, 8, 12, 38, 38, 96, 75, 178, 132, 298
  • 2, 8, 13, 40, 37, 95, 77, 178, 130, 297
  • 2, 8, 14, 42, 40, 102, 79, 189, 135, 302
  • 3, 11, 14, 44, 39, 102, 83, 188, 140, 322
  • 3, 11, 14, 46, 41, 101, 84, 199, 138, 306
  • 3, 11, 15, 44, 40, 105, 84, 193, 140, 318
  • 3, 11, 16, 48, 43, 109, 90, 208, 144, 321
  • 3, 12, 15, 42, 39, 104, 81, 194, 143, 310
  • 3, 12, 16, 45, 42, 109, 85, 197, 142, 319
  • 3, 12, 16, 46, 43, 108, 84, 198, 143, 320
  • 3, 13, 16, 44, 43, 110, 82, 193, 141, 311
  • 4, 6, 26, 28, 70, 60, 151, 111, 254, 177
  • 4, 7, 28, 28, 70, 60, 153, 111, 250, 181
  • 4, 7, 28, 28, 73, 62, 150, 111, 252, 177
  • 5, 8, 26, 26, 74, 63, 152, 114, 254, 178
  • 6, 8, 24, 25, 74, 60, 142, 111, 256, 176
  • 6, 9, 26, 28, 80, 64, 150, 115, 263, 179
  • 6, 10, 30, 30, 82, 70, 164, 114, 268, 186
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