Structure 2020292

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Citation: Matsushita, Nobuyuki; Taira, Ayako (2015). A one-dimensional chloride-bridged PtII/PtIVmixed-valence complex with a 4-[(4-hydroxyphenyl)diazenyl]benzenesulfonate counter-ion. Acta Crystallographica Section C Structural Chemistry, 71, pp. -.

Formula: C56 H72 Cl2 N16 O18 Pt2 S4

Chemical name: <i>catena</i>-Poly[[[bis(ethylenediamine-\k^2^<i>N</i>,<i>N</i>')platinum(II)]-\m-chlorido-[bis(ethylenediamine)platinum(IV)]-\m-chlorido]tetrakis{4-[(4-hydroxyphenyl)diazenyl]benzenesulfonate} dihydrate]

Cell parameters:

  • a = 18.0782(7) Å
  • b = 5.8922(3) Å
  • c = 15.8365(3) Å
  • α = 90°
  • β = 93.7245(7)°
  • γ = 90°

List type: interleaving

List: 1D

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Molecules

CIF datablock 4, entity 5 of 2

Basis: (0;1;0)

Dimensionality: 1

Formula: C4 H16 Cl2 N4 Pt (C4 H16 Cl2 N4 Pt)

Multiplicity: 1

span 1 {1 1 1}

CIF datablock 5, entity 6 of 2

Basis: (0;1;0)

Dimensionality: 1

Formula: C4 H16 Cl2 N4 Pt (C4 H16 Cl2 N4 Pt)

Multiplicity: 1

span 1 {1 1 1}