Structure 2020315

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Citation: Qin, Ying-Lian; Yao, Chen-Zhong; Yang, Bin-Wu; Qin, Jian-Fang; Gong, Qiao-Juan (2016). Synthesis, crystal structure and magnetic properties of a two-dimensional cyanide-based heterometallic coordination polymer with cationic piperazinium ligands: poly[aquatetra-\m~2~-cyanido-\k^8^C:N-dicyanido-\k^2^C-(piperazinium-\kN^4^)cobalt(III)copper(II)]. Acta Crystallographica Section C, 72, pp. 21-27.

Formula: C10 H13 Co Cu N8 O

Chemical name: Poly[aquatetra-\m~2~-cyanido-\k^8^<i>C</i>:<i>N</i>-dicyanido-\k^2^<i>C</i>-(piperazinium-\k<i>N</i>^4^)cobalt(III)copper(II)]

Cell parameters:

  • a = 7.2703(4) Å
  • b = 14.6512(7) Å
  • c = 13.8246(9) Å
  • α = 90.00°
  • β = 90.00°
  • γ = 90.00°

List type: interleaving

List: 2D

Combined 3D structure and graph

span 1 {1 1 1}
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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 2

Basis: (1;0;0 0;0;1)

Dimensionality: 2

Formula: C20 H30 Co2 Cu2 N16 O2 (C10 H15 Co Cu N8 O)

Multiplicity: 1

span 1 {1 1 1}

CIF datablock 1, entity 2 of 2

Basis: (1;0;0 0;0;1)

Dimensionality: 2

Formula: C20 H30 Co2 Cu2 N16 O2 (C10 H15 Co Cu N8 O)

Multiplicity: 1

span 1 {1 1 1}