Structure 2021182

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Citation: Sharko, Anastasiya V.; Erhart, Oliver; Krautscheid, Harald; Domasevitch, Kostiantyn V. (2018). Making an order: the concerted alignment of [MOF~5~]^2{-^} (M = Nb and Ta) dipolar anions in one-dimensional coordination chains sustained by tris(3,4,5-trimethyl-1H-pyrazole)copper(II). Acta Crystallographica Section C, 74, pp. -.

Formula: C18 H30 Cu F5 N6 Nb O

Chemical name: <i>catena</i>-Poly[[tris(3,4,5-trimethyl-1<i>H</i>-pyrazole-\k<i>N</i>^2^)copper(II)]-\m-oxido-[tetrafluoridoniobium(V)]-\m-fluorido]

Cell parameters:

  • a = 9.3311(4) Å
  • b = 13.2097(5) Å
  • c = 19.9741(9) Å
  • α = 90°
  • β = 93.275(5)°
  • γ = 90°

List type: interleaving

List: 1D

Combined 3D structure and graph

span 1 {1 1 1}
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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 2

Basis: (0;1;0)

Dimensionality: 1

Formula: C36 H60 Cu2 F10 N12 Nb2 O2 (C18 H30 Cu F5 N6 Nb O)

Multiplicity: 1

span 1 {1 1 1}

CIF datablock 1, entity 2 of 2

Basis: (0;1;0)

Dimensionality: 1

Formula: C36 H60 Cu2 F10 N12 Nb2 O2 (C18 H30 Cu F5 N6 Nb O)

Multiplicity: 1

span 1 {1 1 1}