Structure 2021789

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Citation: Lan, Wenlong; Zhou, Zhen; Li, Jie; Dou, Yong; Hao, Xiaoyun; Yang, Lu; Liu, Hui; Li, Dacheng; Liu, Qingyun; Zhang, Daopeng (2019). A cyanide-bridged Fe^III^--Mn^II^ heterobimetallic one-dimensional coordination polymer: synthesis, crystal structure, experimental and theoretical magnetism investigation. Acta Crystallographica Section C, 75, pp. -.

Formula: C42 H36 Cl Fe Mn N10 O8

Chemical name: <i>catena</i>-Poly[[[<i>N</i>,<i>N</i>'-(1,2-phenylene)bis(pyridine-2-carboxamidato)-\k^4^<i>N</i>,<i>N</i>',<i>N</i>'',<i>N</i>''']iron(III)]-\m-cyanido-\k^2^<i>C</i>:<i>N</i>-[bis(4,4'-bipyridine-\k<i>N</i>)bis(methanol-\k<i>O</i>)manganese(II)]-\m-cyanido-\k^2^<i>N</i>:<i>C</i>]

Cell parameters:

  • a = 10.404(3) Å
  • b = 13.969(4) Å
  • c = 16.226(4) Å
  • α = 113.317(4)°
  • β = 104.231(4)°
  • γ = 90.973(4)°

List type: interleaving

List: 1D

Combined 3D structure and graph

span 1 {1 1 1}
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Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 2

Basis: (1;0;0)

Dimensionality: 1

Formula: C42 H36 Fe Mn N10 O4 (C42 H36 Fe Mn N10 O4)

Multiplicity: 1

span 1 {1 1 1}

CIF datablock 1, entity 2 of 2

Basis: (1;0;0)

Dimensionality: 1

Formula: C42 H36 Fe Mn N10 O4 (C42 H36 Fe Mn N10 O4)

Multiplicity: 1

span 1 {1 1 1}