Structure 2022688

2022684 << 2022688 >> 2022708
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Citation: Kong, Yu-Jie; Wang, Jian-Teng; Song, Li (2022). A new heteroleptic cuprous polymer constructed by a cyanopyridine ligand exhibiting a supramolecular framework structure and luminescence. Acta Crystallographica Section C, 78, pp. -.

Formula: C48 H42 Cl6 Cu F6 N2 O P3

Chemical name: <i>catena</i>-Poly[[[(9,9-dimethyl-9<i>H</i>-xanthene-4,5-diyl)bis(diphenylphosphane)-\k^2^<i>P</i>,<i>P</i>'](pyridine-3-carbonitrile-\k<i>N</i>^3^)copper(I)] hexafluorophosphate dichloromethane trisolvate]

Cell parameters:

  • a = 15.0438(7) Å
  • b = 13.4200(5) Å
  • c = 25.3937(9) Å
  • α = 90°
  • β = 100.933(4)°
  • γ = 90°

List type: interleaving

List: 1D

Combined 3D structure and graph

span 1 {1 1 1}
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Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 2

Basis: (0;1;0)

Dimensionality: 1

Formula: C90 H72 Cu2 N4 O2 P4 (C45 H36 Cu N2 O P2)

Multiplicity: 1

span 1 {1 1 1}

CIF datablock 1, entity 2 of 2

Basis: (0;1;0)

Dimensionality: 1

Formula: C90 H72 Cu2 N4 O2 P4 (C45 H36 Cu N2 O P2)

Multiplicity: 1

span 1 {1 1 1}