Structure 2103928

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Citation: Gougeon, P.; Gall, P.; Halet, J.-F.; Gautier, R. (2003). Structural trends and the electronic structure of the rare-earth oxomolybdates RMo~5~O~8~ (R = La, Ce, Pr, Nd, Sm, Eu and Gd) containing chains of bioctahedral Mo~10~ clusters. Acta Crystallographica Section B, 59, pp. 472-478.

Formula: Eu Mo5 O8

Chemical name: ?

Cell parameters:

  • a = 7.55540(10) Å
  • b = 9.1622(2) Å
  • c = 9.9685(2) Å
  • α = 90.00°
  • β = 109.3560(9)°
  • γ = 90.00°

List type: noninterleaving

List: 3D

Combined 3D structure and graph

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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 1

Basis: (1;0;0 0;1;0 0;0;1)

Dimensionality: 3

Formula: Eu4 Mo20 O32 (Eu Mo5 O8)

Multiplicity: 1

Coordination sequences:

  • 4, 32, 86, 193, 319, 511, 718, 989, 1275, 1618
  • 4, 32, 88, 194, 330, 520, 744, 1015, 1307, 1671
  • 4, 36, 91, 183, 326, 509, 740, 998, 1290, 1640
  • 4, 37, 97, 188, 333, 511, 745, 998, 1300, 1631
  • 4, 38, 98, 202, 342, 540, 757, 1030, 1320, 1680
  • 4, 38, 103, 202, 352, 530, 779, 1034, 1341, 1692
  • 5, 38, 107, 210, 364, 552, 776, 1052, 1342, 1687
  • 5, 41, 104, 208, 361, 536, 782, 1034, 1336, 1673
  • 11, 34, 99, 201, 348, 551, 776, 1060, 1380, 1702
  • 11, 40, 109, 220, 360, 568, 782, 1067, 1364, 1728
  • 12, 42, 109, 222, 365, 569, 800, 1086, 1384, 1736
  • 12, 49, 121, 232, 381, 587, 813, 1094, 1397, 1758
  • 13, 45, 116, 223, 385, 574, 813, 1087, 1398, 1722
  • 17, 61, 138, 259, 420, 608, 861, 1112, 1437, 1771
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