Structure 2106970

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Citation: Gramaccioli, C.M.; Liborio, G.; Pilati, T. (1981). Structure of Medaite, Mn6 (V Si5 O18 (O H)): The Presence of a New Kind of Heteropolysilicate Anion. Acta Crystallographica B (24,1968-38,1982), 37, pp. 1972-1978.

Formula: H Mn6 O19 Si5 V

Chemical name: Mn6 (V Si5 O18 (O H))

Cell parameters:

  • a = 6.712 Å
  • b = 28.948 Å
  • c = 7.578 Å
  • α = 90°
  • β = 95.4°
  • γ = 90°

List type: noninterleaving

List: 3D

Combined 3D structure and graph

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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 1

Basis: (1;0;0 0;1;0 0;0;1)

Dimensionality: 3

Formula: H4 Mn24 O76 Si20 V4 (H Mn6 O19 Si5 V)

Multiplicity: 1

Coordination sequences:

  • 1, 2, 8, 14, 40, 44, 96, 95, 181, 155
  • 2, 6, 10, 36, 45, 89, 86, 172, 149, 265
  • 2, 6, 11, 33, 40, 86, 84, 164, 147, 274
  • 2, 6, 11, 35, 42, 92, 89, 165, 151, 282
  • 2, 6, 12, 34, 40, 87, 87, 166, 150, 279
  • 3, 8, 14, 40, 44, 96, 95, 181, 155, 280
  • 3, 9, 16, 43, 47, 102, 100, 190, 160, 289
  • 3, 10, 17, 42, 46, 101, 94, 185, 167, 295
  • 3, 10, 17, 46, 50, 105, 99, 189, 165, 299
  • 3, 10, 18, 45, 46, 100, 97, 187, 162, 289
  • 3, 11, 18, 43, 46, 101, 101, 192, 161, 293
  • 3, 12, 17, 45, 51, 102, 94, 184, 160, 281
  • 3, 12, 18, 46, 50, 103, 100, 187, 157, 292
  • 3, 12, 18, 47, 51, 103, 97, 186, 159, 289
  • 3, 12, 19, 45, 47, 103, 98, 179, 154, 288
  • 4, 7, 22, 29, 66, 67, 136, 127, 241, 201
  • 4, 7, 22, 30, 68, 69, 140, 125, 234, 206
  • 4, 7, 22, 30, 69, 71, 139, 126, 240, 205
  • 4, 7, 24, 32, 74, 75, 141, 126, 242, 207
  • 4, 7, 26, 34, 70, 69, 144, 129, 229, 189
  • 4, 8, 24, 31, 70, 72, 146, 127, 233, 201
  • 4, 8, 25, 31, 73, 73, 140, 130, 244, 200
  • 4, 13, 17, 44, 50, 99, 94, 188, 164, 293
  • 4, 13, 18, 46, 50, 103, 96, 187, 161, 291
  • 4, 14, 18, 41, 47, 103, 97, 189, 164, 290
  • 4, 14, 19, 47, 51, 107, 98, 189, 168, 294
  • 4, 15, 20, 48, 54, 109, 98, 187, 167, 298
  • 5, 8, 24, 32, 69, 68, 146, 132, 232, 199
  • 6, 10, 27, 32, 75, 76, 142, 127, 239, 200
  • 6, 10, 28, 35, 78, 75, 146, 130, 238, 202
  • 6, 11, 28, 31, 70, 73, 149, 130, 235, 206
  • 6, 11, 28, 33, 75, 71, 139, 126, 233, 204
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