Structure 2109021

2109020 << 2109021 >> 2109022
Original COD entry Download CIF Download DOT

Citation: Cametti, Georgia; Nagashima, Mariko; Churakov, Sergey V. (2022). Role of lone-pair electron localization in temperature-induced phase transitions in mimetite. Acta Crystallographica Section B, 78, pp. -.

Formula: As4 Cl1.33 O16 Pb6.67

Cell parameters:

  • a = 10.2378(3) Å
  • b = 20.4573(7) Å
  • c = 7.4457(2) Å
  • α = 90°
  • β = 90°
  • γ = 120.039(5)°

List type: noninterleaving

List: 3D

Combined 3D structure and graph

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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 1

Basis: (1;0;0 0;1;0 0;0;1)

Dimensionality: 3

Formula: As12 O60 Pb20 (As3 O15 Pb5)

Multiplicity: 1

Coordination sequences:

  • 2, 5, 6, 14, 15, 40, 35, 79, 67, 140
  • 2, 5, 6, 14, 15, 40, 35, 81, 71, 139
  • 2, 5, 6, 15, 21, 42, 35, 87, 70, 154
  • 2, 6, 7, 14, 19, 40, 36, 70, 73, 126
  • 2, 6, 9, 16, 21, 50, 44, 93, 69, 163
  • 2, 6, 9, 16, 21, 51, 46, 92, 71, 169
  • 2, 7, 8, 22, 20, 48, 41, 86, 88, 161
  • 3, 3, 9, 11, 22, 24, 67, 49, 104, 100
  • 3, 4, 13, 13, 33, 31, 68, 57, 112, 111
  • 3, 6, 8, 25, 19, 48, 44, 87, 83, 160
  • 3, 6, 8, 25, 24, 46, 40, 93, 82, 169
  • 3, 7, 7, 18, 20, 42, 41, 88, 66, 149
  • 3, 9, 9, 21, 26, 49, 39, 86, 95, 147
  • 3, 9, 9, 23, 21, 50, 42, 86, 76, 161
  • 3, 9, 10, 21, 25, 39, 48, 83, 89, 153
  • 4, 5, 11, 12, 38, 30, 64, 64, 126, 110
  • 4, 5, 11, 16, 37, 33, 68, 59, 140, 105
  • 4, 6, 12, 14, 31, 35, 77, 58, 123, 102
  • 4, 7, 20, 16, 37, 33, 73, 65, 125, 121
  • 4, 10, 9, 25, 27, 51, 44, 104, 88, 170
  • 4, 11, 11, 27, 21, 48, 48, 97, 85, 175
  • 5, 5, 18, 17, 34, 30, 70, 67, 131, 110
  • 7, 6, 14, 15, 39, 34, 66, 56, 131, 111
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