Structure 2204519

2204505 << 2204519 >> 2204534
Original COD entry Download CIF Download DOT

Citation: Li, Yanping; Yang, Pin; Huang, Zixiang; Xie, Fuxin (2004). A novel one-dimensional polymeric complex of a tetraaza-macrocycle--copper(II) unit with a [Cu(C~2~O~4~)~2~(CH~3~CN)]^2{--^} bridging anion. Acta Crystallographica Section E, 60, pp. m1710-m1712.

Formula: C84 H114 Cl2 Cu5 N14 O24

Chemical name: catena-poly[(5,12-dimethyl-7,14-diphenyl-1,4,8,11-tetracyclotetradecane)copper(II) bis[[(5,12-dimethyl-7,14-diphenyl-1,4,8,11-tetracyclotetradecane)copper(II)]-\m-oxalato-[(acetonitrile)copper(II)]-\m-oxalato] diperchlorate]

Cell parameters:

  • a = 11.2419(5) Å
  • b = 14.5966(7) Å
  • c = 15.8730(8) Å
  • α = 64.8130(12)°
  • β = 86.6890(12)°
  • γ = 81.0760(12)°

List type: noninterleaving

List: 1D

Combined 3D structure and graph

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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 1

Basis: (1;0;-1)

Dimensionality: 1

Formula: C56 H72 Cu4 N8 O16 (C14 H18 Cu N2 O4)

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