Structure 2208196

2208195 << 2208196 >> 2208214
Original COD entry Download CIF Download DOT

Citation: Salloum, D.; Gougeon, P.; Potel, M. (2006). Na~2.54~Cs~1.14~Mo~9~S~11~, a quaternary reduced molybdenum sulfide containing Mo~9~ clusters.. Acta Crystallographica, Section E, 62, pp. 35-i37.

Formula: Cs1.14 Mo9 Na2.54 S11

Chemical name: Sodium caesium nonamolybdenum undecasulfide

Cell parameters:

  • a = 9.8888(2) Å
  • b = 9.8888(2) Å
  • c = 11.6398(3) Å
  • α = 90.00°
  • β = 90.00°
  • γ = 120.00°

List type: interleaving

List: 1-3D

Combined 3D structure and graph

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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 2

Basis: (1;0;0 0;1;0 0;0;1)

Dimensionality: 3

Formula: Mo18 S22 (Mo9 S11)

Multiplicity: 1

Coordination sequences:

  • 3, 12, 15, 43, 60, 112, 147, 188, 267, 310
  • 4, 15, 14, 44, 73, 98, 154, 223, 268, 289
  • 4, 20, 25, 48, 93, 124, 170, 237, 297, 332
  • 9, 15, 29, 54, 93, 127, 172, 244, 283, 347
  • 10, 15, 24, 62, 79, 122, 188, 251, 270, 327
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CIF datablock 1, entity 2 of 2

Basis: (0;0;1)

Dimensionality: 1

Formula: Cs6 (Cs)

Multiplicity: 1

Coordination sequences:

  • 2, 2, 4, 2, 4, 2, 4, 2, 4, 2
  • 3, 3, 3, 3, 3, 3, 3, 3, 3, 3
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