Structure 2209680

2209679 << 2209680 >> 2209681
Original COD entry Download CIF Download DOT

Citation: Gall, P.; Gougeon, P. (2006). Redetermination of Mn~1.44~Mo~8~O~11~: evidence of pairwise distortion of octahedral molybdenum chains. Acta Crystallographica, Section E, 62, pp. m155-m157.

Formula: Mn1.44 Mo8 O11

Chemical name: manganese octamolybdenum undecaoxide

Cell parameters:

  • a = 5.6971(3) Å
  • b = 16.9333(12) Å
  • c = 9.8658(8) Å
  • α = 90.00°
  • β = 94.900(6)°
  • γ = 90.00°

List type: noninterleaving

List: 3D

Combined 3D structure and graph

span 1 {1 1 1}
Ctrl-click to select multiple nodes

JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 1

Basis: (1;0;0 0;1;0 0;0;1)

Dimensionality: 3

Formula: Mn12 Mo32 O44 (Mn3 Mo8 O11)

Multiplicity: 1

Coordination sequences:

  • 3, 27, 76, 131, 221, 336, 469, 623, 805, 991
  • 3, 28, 75, 128, 222, 332, 470, 645, 794, 1002
  • 4, 28, 72, 129, 220, 326, 480, 635, 785, 970
  • 4, 29, 73, 131, 214, 328, 472, 633, 780, 976
  • 4, 30, 76, 122, 250, 364, 470, 608, 856, 1052
  • 4, 30, 78, 124, 246, 364, 466, 626, 856, 1074
  • 5, 28, 62, 122, 221, 331, 451, 600, 822, 1027
  • 5, 28, 65, 128, 216, 315, 466, 616, 806, 982
  • 5, 30, 70, 136, 217, 352, 467, 636, 809, 1044
  • 5, 31, 68, 137, 225, 348, 479, 624, 823, 1052
  • 6, 31, 67, 134, 227, 343, 464, 633, 845, 1036
  • 6, 31, 73, 138, 222, 331, 479, 639, 799, 1024
  • 7, 23, 72, 125, 207, 331, 479, 609, 803, 1008
  • 8, 24, 73, 133, 211, 347, 465, 630, 826, 1043
  • 9, 27, 80, 140, 225, 367, 470, 637, 861, 1039
  • 11, 36, 82, 157, 240, 362, 505, 669, 849, 1085
  • 11, 37, 82, 160, 246, 358, 510, 672, 837, 1100
  • 12, 39, 85, 155, 252, 381, 521, 688, 842, 1087
  • 12, 40, 78, 154, 254, 352, 483, 671, 858, 1067
  • 12, 42, 87, 162, 275, 384, 506, 688, 909, 1092
  • 12, 43, 85, 162, 272, 374, 515, 672, 902, 1084
  • 13, 40, 78, 153, 250, 357, 500, 673, 847, 1072
  • 13, 42, 89, 160, 255, 379, 524, 684, 853, 1094
span 1 {1 1 1}