Structure 2231813

2231796 << 2231813 >> 2231853
Original COD entry Download CIF Download DOT

Citation: Zhou, Hui; Upreti, Shailesh; Chernova, Natasha A.; Whittingham, M. Stanley (2011). Lithium cobalt(II) pyrophosphate, Li~1.86~CoP~2~O~7~, from synchrotron X-ray powder data. Acta Crystallographica Section E, 67, pp. i58-i59.

Formula: Co Li1.865 O7 P2

Chemical name: Lithium cobalt(II) pyrophosphate

Cell parameters:

  • a = 9.76453(4) Å
  • b = 9.69622(4) Å
  • c = 10.95952(4) Å
  • α = 90.0°
  • β = 101.7664(2)°
  • γ = 90.0°

List type: noninterleaving

List: 3D

Combined 3D structure and graph

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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 1

Basis: (1;0;0 0;1;0 0;0;1)

Dimensionality: 3

Formula: Co12 Li8 O56 P16 (Co3 Li2 O14 P4)

Multiplicity: 1

Coordination sequences:

  • 1, 2, 7, 10, 32, 27, 67, 55, 145, 107
  • 1, 3, 5, 14, 18, 55, 41, 103, 87, 201
  • 1, 3, 6, 21, 22, 57, 45, 110, 80, 192
  • 1, 5, 8, 22, 23, 63, 46, 109, 81, 198
  • 2, 6, 6, 21, 29, 77, 56, 134, 106, 237
  • 2, 6, 8, 29, 30, 70, 51, 126, 96, 221
  • 2, 8, 9, 29, 30, 82, 69, 159, 111, 238
  • 2, 8, 10, 31, 33, 86, 71, 165, 112, 240
  • 2, 8, 10, 32, 32, 84, 73, 170, 112, 241
  • 2, 8, 11, 32, 30, 75, 53, 128, 97, 226
  • 3, 7, 10, 32, 27, 67, 55, 145, 107, 237
  • 3, 11, 13, 33, 27, 79, 67, 149, 108, 249
  • 3, 11, 13, 35, 31, 77, 55, 135, 103, 247
  • 3, 12, 13, 36, 30, 79, 71, 163, 102, 230
  • 3, 12, 15, 38, 30, 78, 61, 150, 109, 255
  • 4, 4, 17, 21, 56, 52, 132, 95, 203, 138
  • 4, 5, 14, 18, 55, 41, 103, 87, 201, 134
  • 4, 6, 21, 22, 57, 45, 110, 80, 192, 140
  • 4, 6, 22, 21, 51, 44, 112, 78, 179, 134
  • 4, 14, 15, 39, 34, 90, 67, 153, 111, 255
  • 5, 9, 26, 20, 49, 44, 116, 82, 194, 142
  • 6, 8, 22, 23, 63, 46, 109, 81, 198, 150
  • 6, 8, 23, 22, 63, 57, 132, 95, 210, 139
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