Structure 2237722

2237694 << 2237722 >> 2237725
Original COD entry Download CIF Download DOT

Citation: Xiao, Linda; Bhadbhade, Mohan; Baker, Anthony T. (2013). catena-Poly[[copper(I)-\m-2,6-bis[4-(pyridin-2-yl)thiazol-2-yl]pyridine] hexafluoridophosphate acetonitrile monosolvate] from single-crystal synchrotron data. Acta Crystallographica Section E, 69, pp. m231-.

Formula: C23 H16 Cu F6 N6 P S2

Chemical name: <i>catena</i>-Poly[[copper(I)-\m-2,6-bis[4-(pyridin-2-yl)thiazol-2-yl]pyridine]hexafluoridophosphate acetonitrile monosolvate]

Cell parameters:

  • a = 12.525(3) Å
  • b = 13.950(3) Å
  • c = 14.626(3) Å
  • α = 90.00°
  • β = 97.72(3)°
  • γ = 90.00°

List type: interleaving

List: 1D

Combined 3D structure and graph

span 1 {1 1 1}
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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 2

Basis: (0;1;0)

Dimensionality: 1

Formula: C42 H26 Cu2 N10 S4 (C21 H13 Cu N5 S2)

Multiplicity: 1

Coordination sequences:

  • 1, 2, 3, 4, 7, 10, 10, 9, 7, 8
  • 1, 2, 4, 3, 3, 5, 5, 8, 9, 7
  • 1, 2, 4, 3, 4, 6, 9, 8, 7, 6
  • 1, 2, 4, 3, 4, 6, 10, 12, 20, 16
  • 1, 2, 4, 4, 4, 7, 9, 15, 14, 14
  • 1, 2, 4, 5, 6, 5, 8, 9, 7, 6
  • 1, 2, 4, 6, 7, 9, 8, 7, 6, 6
  • 2, 4, 4, 7, 10, 12, 10, 9, 9, 13
  • 2, 4, 7, 7, 10, 12, 20, 16, 8, 6
  • 3, 3, 4, 7, 10, 10, 9, 7, 8, 9
  • 3, 4, 3, 3, 5, 5, 8, 9, 7, 6
  • 3, 4, 3, 4, 6, 9, 8, 7, 6, 6
  • 3, 4, 3, 4, 6, 10, 12, 20, 16, 8
  • 3, 4, 4, 4, 7, 9, 15, 14, 14, 11
  • 3, 4, 5, 6, 5, 8, 9, 7, 6, 6
  • 3, 4, 6, 7, 9, 8, 7, 6, 6, 6
  • 3, 5, 6, 8, 9, 15, 14, 14, 11, 7
  • 3, 5, 8, 9, 13, 11, 9, 9, 13, 11
  • 3, 6, 6, 9, 10, 9, 7, 6, 8, 9
  • 3, 6, 8, 6, 8, 9, 7, 6, 6, 8
  • 3, 7, 9, 10, 8, 7, 6, 6, 6, 10
  • 3, 7, 9, 13, 11, 7, 6, 8, 9, 15
  • 4, 8, 12, 12, 8, 6, 6, 6, 10, 12
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CIF datablock 1, entity 2 of 2

Basis: (0;1;0)

Dimensionality: 1

Formula: C42 H26 Cu2 N10 S4 (C21 H13 Cu N5 S2)

Multiplicity: 1

Coordination sequences:

  • 1, 2, 3, 4, 7, 10, 10, 9, 7, 8
  • 1, 2, 4, 3, 3, 5, 5, 8, 9, 7
  • 1, 2, 4, 3, 4, 6, 9, 8, 7, 6
  • 1, 2, 4, 3, 4, 6, 10, 12, 20, 16
  • 1, 2, 4, 4, 4, 7, 9, 15, 14, 14
  • 1, 2, 4, 5, 6, 5, 8, 9, 7, 6
  • 1, 2, 4, 6, 7, 9, 8, 7, 6, 6
  • 2, 4, 4, 7, 10, 12, 10, 9, 9, 13
  • 2, 4, 7, 7, 10, 12, 20, 16, 8, 6
  • 3, 3, 4, 7, 10, 10, 9, 7, 8, 9
  • 3, 4, 3, 3, 5, 5, 8, 9, 7, 6
  • 3, 4, 3, 4, 6, 9, 8, 7, 6, 6
  • 3, 4, 3, 4, 6, 10, 12, 20, 16, 8
  • 3, 4, 4, 4, 7, 9, 15, 14, 14, 11
  • 3, 4, 5, 6, 5, 8, 9, 7, 6, 6
  • 3, 4, 6, 7, 9, 8, 7, 6, 6, 6
  • 3, 5, 6, 8, 9, 15, 14, 14, 11, 7
  • 3, 5, 8, 9, 13, 11, 9, 9, 13, 11
  • 3, 6, 6, 9, 10, 9, 7, 6, 8, 9
  • 3, 6, 8, 6, 8, 9, 7, 6, 6, 8
  • 3, 7, 9, 10, 8, 7, 6, 6, 6, 10
  • 3, 7, 9, 13, 11, 7, 6, 8, 9, 15
  • 4, 8, 12, 12, 8, 6, 6, 6, 10, 12
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