Structure 2239996

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Citation: Stoscup, Julie A.; Staples, Richard J.; Biros, Shannon M. (2014). Crystal structure of a samarium(III) nitrate chain cross-linked by a bis-carbamoylmethylphosphine oxide ligand. Acta Crystallographica Section E, 70, pp. 188-191.

Formula: C14 H32 N8 O27 P2 Sm2

Chemical name: Poly[aquabis(\m-nitrato-\k^4^<i>O</i>,<i>O</i>':<i>O</i>,<i>O</i>'')tetrakis(nitrato-\k^2^<i>O</i>,<i>O</i>'){\m~4~-tetraethyl[(ethane-1,2-diyl)bis(azanediyl)bis(2-oxoethane-2,1-diyl)]diphosphonate-\k^2^<i>O</i>,<i>O</i>'}disamarium(III)]

Cell parameters:

  • a = 8.9416(7) Å
  • b = 11.0128(9) Å
  • c = 18.4635(15) Å
  • α = 81.4410(10)°
  • β = 83.4280(10)°
  • γ = 86.9770(10)°

List type: noninterleaving

List: 2D

Combined 3D structure and graph

span 1 {1 1 1}
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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 1

Basis: (1;0;0 0;0;1)

Dimensionality: 2

Formula: C28 H64 N16 O54 P4 Sm4 (C14 H32 N8 O27 P2 Sm2)

Multiplicity: 1

span 1 {1 1 1}