Structure 2241638

2241623 << 2241638 >> 2241657
Original COD entry Download CIF Download DOT

Citation: David, R\'enald (2016). Synthesis and crystal structure of Na~4~Ni~7~(AsO~4~)~6~. Acta Crystallographica Section E, 72, pp. 632-634.

Formula: As6 Na4 Ni7 O24

Chemical name: Tetrasodium heptanickel hexaarsenate

Cell parameters:

  • a = 14.5383(11) Å
  • b = 14.5047(11) Å
  • c = 10.6120(8) Å
  • α = 90°
  • β = 118.299(2)°
  • γ = 90°

List type: noninterleaving

List: 3D

Combined 3D structure and graph

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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 1

Basis: (1;0;0 0;1;0 0;0;1)

Dimensionality: 3

Formula: As24 Ni32 O96 (As3 Ni4 O12)

Multiplicity: 1

Coordination sequences:

  • 1, 3, 5, 35, 46, 62, 118, 162, 228, 262
  • 2, 8, 11, 47, 61, 98, 156, 191, 279, 311
  • 2, 10, 19, 40, 59, 88, 156, 181, 283, 339
  • 2, 13, 30, 58, 72, 127, 196, 245, 299, 373
  • 2, 14, 31, 54, 77, 132, 192, 241, 310, 377
  • 3, 13, 14, 48, 50, 108, 143, 227, 256, 368
  • 3, 14, 21, 51, 72, 109, 178, 222, 303, 365
  • 3, 14, 23, 45, 66, 117, 160, 217, 289, 316
  • 3, 15, 25, 54, 78, 128, 173, 213, 307, 368
  • 3, 17, 23, 54, 76, 131, 164, 234, 289, 363
  • 3, 19, 26, 51, 84, 115, 183, 217, 296, 356
  • 4, 5, 35, 46, 62, 118, 162, 228, 262, 371
  • 4, 18, 26, 47, 82, 125, 168, 232, 292, 373
  • 4, 19, 24, 52, 77, 136, 164, 244, 287, 347
  • 4, 20, 27, 48, 86, 114, 186, 233, 316, 383
  • 6, 10, 36, 48, 74, 130, 160, 246, 316, 398
  • 6, 10, 36, 54, 94, 132, 174, 260, 290, 400
  • 6, 13, 28, 48, 66, 122, 160, 243, 297, 391
  • 6, 13, 33, 54, 85, 127, 197, 248, 304, 385
  • 6, 15, 37, 52, 92, 132, 192, 238, 312, 392
  • 9, 11, 29, 47, 78, 113, 189, 217, 315, 386
  • 9, 18, 35, 53, 93, 139, 191, 254, 305, 389
  • 9, 20, 32, 57, 90, 145, 182, 250, 311, 396
  • 10, 21, 36, 56, 102, 146, 191, 250, 318, 389
  • 12, 22, 31, 61, 98, 149, 187, 266, 294, 398
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