Structure 2243346

2243320 << 2243346 >> 2243347
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Citation: Gavrish, Sergey P.; Shova, Sergiu; Cazacu, Maria; Dascalu, Mihaela; Lampeka, Yaroslaw D. (2020). Syntheses and crystal structures of the one-dimensional coordination polymers formed by [Ni(cyclam)]^2+^ cations and 1,3-bis(3-carboxypropyl)tetramethyldisiloxane anions in different degrees of deprotonation. Acta Crystallographica Section E, 76, pp. 446-451.

Formula: C22 H48 N4 Ni O5 Si2

Chemical name: <i>catena</i>-Poly[[(1,4,8,11-tetraazacyclotetradecane-\k^4^<i>N</i>^1^,<i>N</i>^4^,<i>N</i>^8^,<i>N</i>^11^)nickel(II)]-\m-1,3-bis(3-carboxylatopropyl)tetramethyldisiloxane-\k^2^<i>O</i>:<i>O</i>']

Cell parameters:

  • a = 13.033(5) Å
  • b = 12.877(10) Å
  • c = 9.028(3) Å
  • α = 90°
  • β = 101.31(3)°
  • γ = 90°

List type: interleaving

List: 1D

Combined 3D structure and graph

span 1 {1 1 1}
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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 2

Basis: (1;0;1)

Dimensionality: 1

Formula: C26 H60 N4 Ni O6 Si2 (C26 H60 N4 Ni O6 Si2)

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CIF datablock 1, entity 2 of 2

Basis: (1;0;1)

Dimensionality: 1

Formula: C26 H60 N4 Ni O6 Si2 (C26 H60 N4 Ni O6 Si2)

span 1 {1 1 1}