Structure 2243407

2243406 << 2243407 >> 2243417
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Citation: Gavrish, Sergey P.; Shova, Sergiu; Cazacu, Maria; Lampeka, Yaroslaw D. (2020). Crystal structure of the one-dimensional coordination polymer formed by the macrocyclic [Ni(cyclam)]^2+^ cation and the dianion of diphenylsilanediylbis(4-benzoic acid). Acta Crystallographica Section E, 76, pp. 929-932.

Formula: C72 H90 N8 Ni2 O11 Si2

Chemical name: <i>catena</i>-Poly[[[(1,4,8,11-tetraazacyclotetradecane-\k^4^<i>N</i>^1^,<i>N</i>^4^,<i>N</i>^8^,<i>N</i>^11^)nickel(II)]-\m-4,4'-(diphenylsilanediyl)dibenzoato-\k^2^<i>O</i>:<i>O</i>']sesquihydrate]

Cell parameters:

  • a = 25.390(4) Å
  • b = 7.3865(10) Å
  • c = 18.2424(16) Å
  • α = 90°
  • β = 98.161(10)°
  • γ = 90°

List type: interleaving

List: 1D

Combined 3D structure and graph

span 1 {1 1 1}
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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 2

Basis: (1;0;1)

Dimensionality: 1

Formula: C72 H84 N8 Ni2 O8 Si2 (C36 H42 N4 Ni O4 Si)

span 1 {1 1 1}

CIF datablock 1, entity 2 of 2

Basis: (1;0;1)

Dimensionality: 1

Formula: C72 H84 N8 Ni2 O8 Si2 (C36 H42 N4 Ni O4 Si)

span 1 {1 1 1}