Structure 2243641

2243632 << 2243641 >> 2243657
Original COD entry Download CIF Download DOT

Citation: Taouss, Christina; Calvo, Marina; Jones, Peter G. (2020). Crystal structure of the unusual coordination polymer catena-poly[[gold(I)-\m-1,2-bis(diphenylphosphinothioyl)ethane-\k^2^S:S'] dibromidoaurate(I)]. Acta Crystallographica Section E, 76, pp. 1768-1770.

Formula: C26 H24 Au2 Br2 P2 S2

Chemical name: <i>catena</i>-Poly[[gold(I)-\m-1,2-bis(diphenylphosphinothioyl)ethane-\k^2^<i>S</i>:<i>S</i>'] dibromidoaurate(I)]

Cell parameters:

  • a = 21.4112(8) Å
  • b = 11.9708(2) Å
  • c = 13.7726(4) Å
  • α = 90°
  • β = 128.316(7)°
  • γ = 90°

List type: interleaving

List: 1D

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Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 2

Basis: (0;0;1)

Dimensionality: 1

Formula: C52 H48 Au4 Br4 P4 S4 (C13 H12 Au Br P S)

Multiplicity: 1

span 1 {1 1 1}

CIF datablock 1, entity 2 of 2

Basis: (0;0;1)

Dimensionality: 1

Formula: C52 H48 Au4 Br4 P4 S4 (C13 H12 Au Br P S)

Multiplicity: 1

span 1 {1 1 1}