Structure 2311592

2311565 << 2311592 >> 2311593
Original COD entry Download CIF Download DOT

Citation: Kremer, Marius; Englert, Ulli (2019). Zn and Ni complexes of pyridine-2,6-di-carboxyl-ates: crystal field stabilization matters!. Acta crystallographica. Section E, Crystallographic communications, 75, pp. 903-911.

Formula: C7 H2 Cl N O4 Zn

Chemical name: Poly[(4-chloropyridine-2,6-dicarboxylato)zinc(II)]

Cell parameters:

  • a = 10.0293(5) Å
  • b = 10.0293(5) Å
  • c = 16.8924(9) Å
  • α = 90°
  • β = 90°
  • γ = 90°

List type: interleaving

List: 2D

Combined 3D structure and graph

span 1 {1 1 1}
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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 2

Basis: (1;0;0 0;1;0)

Dimensionality: 2

Formula: C28 H8 Cl4 N4 O16 Zn4 (C7 H2 Cl N O4 Zn)

Multiplicity: 1

Coordination sequences:

  • 1, 2, 4, 3, 5, 4, 10, 14, 18, 28
  • 1, 2, 4, 5, 5, 7, 10, 16, 25, 31
  • 2, 6, 6, 12, 14, 22, 23, 31, 27, 43
  • 2, 6, 8, 12, 13, 21, 22, 32, 32, 42
  • 3, 4, 3, 5, 4, 10, 14, 18, 28, 40
  • 3, 4, 5, 5, 7, 10, 16, 25, 31, 29
  • 3, 4, 10, 10, 12, 15, 31, 28, 30, 33
  • 3, 6, 7, 8, 10, 16, 25, 31, 29, 33
  • 3, 8, 7, 7, 14, 22, 22, 28, 32, 38
  • 5, 6, 8, 11, 21, 20, 24, 26, 42, 36
span 1 {1 1 1}

CIF datablock 1, entity 2 of 2

Basis: (1;0;0 0;1;0)

Dimensionality: 2

Formula: C28 H8 Cl4 N4 O16 Zn4 (C7 H2 Cl N O4 Zn)

Multiplicity: 1

Coordination sequences:

  • 1, 2, 4, 3, 5, 4, 10, 14, 18, 28
  • 1, 2, 4, 5, 5, 7, 10, 16, 25, 31
  • 2, 6, 6, 12, 14, 22, 23, 31, 27, 43
  • 2, 6, 8, 12, 13, 21, 22, 32, 32, 42
  • 3, 4, 3, 5, 4, 10, 14, 18, 28, 40
  • 3, 4, 5, 5, 7, 10, 16, 25, 31, 29
  • 3, 4, 10, 10, 12, 15, 31, 28, 30, 33
  • 3, 6, 7, 8, 10, 16, 25, 31, 29, 33
  • 3, 8, 7, 7, 14, 22, 22, 28, 32, 38
  • 5, 6, 8, 11, 21, 20, 24, 26, 42, 36
span 1 {1 1 1}